Fluorine-Based Strong and Recyclable Biobased Epoxy Vitrimer for Application in Carbon Fiber Reinforced Composites ‌ Xingchen Wang (8358159)

“…The introduction of the fluorine motif formed fluorine–hydrogen bonds, enabling improvement of the mechanical strength of epoxy vitrimers, while the electron-withdrawing effect of fluorine atoms accelerated the exchange of dynamic bonds, thus improving the reprocess performance. …”

Selective Sorption of Organic Molecules by the Flexible Porous Hybrid Metal−Organic Framework MIL-53(Fe) Controlled by Various Host−Guest Interactions ‌ Franck Millange (1678954)

“…Careful dehydration of MIL-53(Fe)[2,6-lutidine,H₂O] provides a new material, MIL-53(Fe)[2,6-lutidine_0.5], with an intermediate unit cell volume: in this case no host−guest hydrogen bonds are formed. Time-resolved in situ energy-dispersive X-ray diffraction shows that when exposed to an aqueous mixture of pyridine and 2,6-lutidine the hydrated MIL-53(Fe) takes up both guest molecules initially to give two distinct phases, but the ultimate product is only MIL-53(Fe)[2,6-lutidine,H₂O].…”

Table1_A photographic method to identify reservoir geohazards induced by rock mass deterioration of hydro-fluctuation belt.doc ‌ Zhenwei Dai (5090993)

“…Aiming at this issue, several typical evolution modes of potential RMD-induced geohazards were generalized, and an unmanned aerial vehicle (UAV) photographic method integrating the orthophotography, three-dimensional multi-angle oblique photography and high-precision digital elevation model (DEM) was proposed to early recognize the newly formed potential RMD-induced geohazards. By resolving the problem of poor precision in the orthophotographic images of high steep bank slopes, the proposed method improved the recognition reliability of potential reservoir geohazards in the HFBs. …”

DinQ translation and localization. ‌ Ragnhild Weel-Sneve (234295)

“…(F) 3D modelling of DinQ as a regular α-helix embedded in a lipid membrane. Polar patch formed by residues Glu17, Arg20 and Gln24 encircled by dashed ellipse.…”

Bis‑<i>N</i>‑Heterocyclic Carbene (NHC) Stabilized η⁶‑Arene Iron(0) Complexes: Synthesis, Structure, Reactivity, and Catalytic Activity ‌ Burgert Blom (1345701)

“…Complex <b>2</b> is unstable in aromatic solvents and forms, <i>via</i> a novel synthetic transformation involving intramolecular reductive elimination and concomitant PMe₃ elimination, the Fe (0) arene complex [Fe­{(^DippC:)₂CH₂}­(η⁶-C₆D₆)] (<b>4-<i>d</i></b>_<b>6</b>) in C₆D<sub>6.…”

The <i>yabG</i> region of the <i>C</i>. <i>difficile</i> chromosome and organization of YabG. ‌ Eleonora Marini (17382854)

“…<i>coli</i>. In F, the indicated forms of YabG were produced together with or in the absence of CspBA The proteins in whole cell extracts were resolved by SDS-PAGE and the gels stained with Coomassie or subject to immunoblotting (in <b>F</b>) with anti-CspB antibodies. …”

Senescence cell progenitor and immortal cell progenitor subtype cell lines correlate with distinct breast tumor subtypes. ‌ Mine Mumcuoglu (246981)

“…Chart displays mean tumor sizes (± S.D.) generated by MDA-MB-231 and T47D cell lines, respectively in female (top) and mala (bottom) mice. T47D cells formed smaller tumors that regressed and completely resolved within 30 days. …”

Synthesis and Structure of Intermediates in Copper-Catalyzed Alkylation of Diphenylphosphine ‌ Matthew F. Cain (2269663)

“…These observations are consistent with a proposed mechanism for catalytic P−C bond formation involving deprotonation of the cationic diphenylphosphine complex [Cu(triphos)(PHPh₂)][PF₆] (<b>12</b>) by NaOSiMe₃ to yield the phosphido complex Cu(triphos)(PPh₂) (<b>22</b>). …”

Rooted phylogenetic tree of 550 base pair E1 fragment produced from Bayesian analysis using BEAST. ‌ Isabel Fourie (11896234)

“…Phylogenetic analysis with strong posterior probability support was obtained as follows: the concatenated (ORF1 and ORF 2) and nsP region placed MIDV in its own complex as seen for analysis using nsP4, while analysis using the sP region placed MIDV within the SF complex as seen with analyses involving the E1 fragment (which forms part of the structural proteins) (Figs <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g003" target="_blank">3</a>, <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g004" target="_blank">4</a> and <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g005" target="_blank">5</a>). …”

Tuning the Inclusion Properties and Solid-State Reactivity of Second Sphere Adducts Using Conformationally Flexible Bidentate Ligands ‌ Fang Guo (105824)

“…We demonstrate that some of the second sphere adducts are dynamic, showing reversible guest release/uptake involving crystalline-to-amorphous-to-crystalline phase transformations. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... ‌ Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Near-isotropic, reconstructed volume electron microscopy (FIB-SEM) of mouse dorsal striatum (jrc_mus-dorsal-striatum) ‌ CellMap Project Team (14322654)

“…Here, we have used focused ion beam-scanning electron microscopy to generate 3D reconstructions of intracellular organelles and their membrane appositions involving the ER (distance ≤30 nm) in different neuronal compartments. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... ‌ Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... ‌ Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Directed Synthesis of the Triangular Mixed-Metal Cluster H₂RhRe₂Cp*(CO)₉: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of C... ‌ Shih-Huang Huang (2148001)

“…On the basis of the first-order rate constants and the Eyring activation parameters (Δ<i>H</i>^⧧ = 25.0(8) kcal/mol; Δ<i>S</i>^⧧ = −2.6(3) eu), a rate-limiting step involving a polyhedral opening of <b>4</b> is supported. …”

Proton-Coupled Electron Transfer to a Molybdenum Ethylene Complex Yields a β‑Agostic Ethyl: Structure, Dynamics and Mechanism ‌ Máté J. Bezdek (1980178)

“…Comparison of p<i>K</i>_a and electrochemical data for the complexes <b>[1-C₂H₄]⁺</b> and <b>[1-NH₃]⁺</b> in combination with a deuterium kinetic isotope effect (<i>k</i>_H/<i>k</i>_D) of 3.5(2) at 23 °C support a PCET process involving initial electron transfer followed by protonation leading to the formation of <b>[1-CH₂CH₃]⁺</b> and <b>[1-NH₂]⁺</b> or a concerted pathway. …”

Directed Synthesis of the Triangular Mixed-Metal Cluster H₂RhRe₂Cp*(CO)₉: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of C... ‌ Shih-Huang Huang (2148001)

“…On the basis of the first-order rate constants and the Eyring activation parameters (Δ<i>H</i>^⧧ = 25.0(8) kcal/mol; Δ<i>S</i>^⧧ = −2.6(3) eu), a rate-limiting step involving a polyhedral opening of <b>4</b> is supported. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... ‌ Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Impact of Photosensitizing Multilayered Structure on Ruthenium(II)-Dye-Sensitized TiO₂‑Nanoparticle Photocatalysts ‌ Sogo Furugori (4275475)

“…Thus, crucial aspects of the energy- and electron-transfer mechanism for the photocatalytic H₂ and O₂ evolution reactions involve not only the Ru­(II)-complex-TiO₂ interface but also the multilayered structure of the Ru­(II)-photosensitizers on the Pt–TiO₂ surface.…”

Multiple sequence alignment of the NpDps4 with a selection of its homolog sequences from six cyanobacterial phylogenetic groups. ‌ Christoph Howe (7114679)

“…Amino acids of the ferroxidase center (FOC) are indicated by an asterisk *A, *B or *A/B indicating the involvement of metal coordination at site A and/or B in regards to the His-type FOC of NpDps4 and TeDpsA. …”