Polyphosphate Ions Encapsulated in Oxothiomolybdate Rings:  Synthesis, Structure, and Behavior in Solution ‌ Emmanuel Cadot (1606021)

“…Nevertheless, <b>1</b> remains labile, and successive equilibria were evidenced and interpreted as an ion-pair association involving a halide ion (Cl, Br, or I), responsible for the conformational change of the {P₂O₇} group within the cavity. …”

Revelation of Varying Coordination Modes and Noninnocence of Deprotonated 2,2′-Bipyridine-3,3′-diol in {Os(bpy)₂} Frameworks ‌ Prabir Ghosh (1625659)

“…The reaction of 2,2′-bipyridine-3,3′-diol (H₂L) and <i>cis</i>-Os^II(bpy)₂­Cl₂ (bpy = 2,2′-bipyridine) results in isomeric forms of [Os^II(bpy)₂(HL^–)]­ClO₄, [<b>1</b>]­ClO₄ and [<b>2</b>]­ClO₄, because of the varying binding modes of partially deprotonated HL^–. …”

The emotional impact of nature seen through the lenses of Virtual Reality (VR) and revealed through the power of expressive art PART 1 ‌ Gabriella Rodolico (11358915)

“…<br><br>We decided to follow a progressive planning starting from an Explorathon (https://www.explorathon.co.uk/) event with a focus on classroom teachers and progressing with a contribution to the Festival of Social Sciences(https://esrc.ukri.org/public-engagement/festival-of-social-science/) (FoSS) by involving the same teachers' classes and a total of 200 pupils from a mainstream and an ASN school. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units ‌ Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

Dimerization of Stu2 is required for kinetochore association. ‌ Matthew P. Miller (2328283)

“…For clarity, cross-links within Ndc80 complex proteins and those involving Stu2 fusion regions (extreme N-terminus and eGFP) are shown in grey. …”

Structural, Electrochemical, and Spectroscopic Investigation of Acetate Bridged Dinuclear Tetrakis-Schiff Base Macrocycles of Mn and Zn ‌ Subhadeep Kal (1720603)

“…The electrochemical and spectroscopic analysis of these complexes will aid in future studies involving electrocatalytic processes with related dinuclear macrocycles.…”

The Dinuclear Zn(II) Complex Catalyzed Cyclization of a Series of 2-Hydroxypropyl Aryl Phosphate RNA Models:  Progressive Change in Mechanism from Rate-Limiting P−O Bond Cleavage t... ‌ Shannon E. Bunn (2438131)

“…The data are analyzed in terms of a multistep process whereby a first formed complex rearranges to a reactive complex with a doubly activated phosphate coordinated to both metal ions. …”

Reversible Switching of the Coordination Modes of a Pyridine-Functionalized Quinonoid Zwitterion; Its Di- and Tetranuclear Palladium Complexes ‌ Alessio Ghisolfi (1588846)

“…This switch modifies the extent of π-delocalization involving the potentially antiaromatic quinonoid moiety and is accompanied by a significant color change, from red in <b>3</b> to green in <b>4</b>. …”

Organometallic Complexes of Scandium and Yttrium Supported by a Bulky Salicylaldimine Ligand ‌ David J. H. Emslie (1425715)

“…These compounds are highly thermally stable, decomposing at temperatures above 140 °C via a pathway involving metalation of one of the N-aryl isopropyl methyl groups. …”

Hormone-independent, EcR-mediated endoreplication of SC DNA is stimulated by mating. ‌ Aaron Leiblich (3211392)

“…(F) Proposed model explaining the different forms of hormone-dependent and hormone-independent, EcR-mediated SC growth in virgin and mated males. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units ‌ Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

[(Cp−CMe₂−Flu)₂Ln]^-[Li(ether)<i>_n</i>]⁺ (Ln = Y, La):  Complexes with Unusual Coordination Modes of the Fluorenyl Ligand and... ‌ Evgueni Kirillov (1425814)

“…The fluorenyl ligands in <b>2</b> show an unprecedented η¹ bonding mode and a rare η³ bonding mode involving, respectively, a carbon atom of a phenyl ring and the bridgehead carbon atom of the central ring and the two adjacent carbon atoms of one six-membered ring. …”

Revelation of Varying Coordination Modes and Noninnocence of Deprotonated 2,2′-Bipyridine-3,3′-diol in {Os(bpy)₂} Frameworks ‌ Prabir Ghosh (1625659)

“…The reaction of 2,2′-bipyridine-3,3′-diol (H₂L) and <i>cis</i>-Os^II(bpy)₂­Cl₂ (bpy = 2,2′-bipyridine) results in isomeric forms of [Os^II(bpy)₂(HL^–)]­ClO₄, [<b>1</b>]­ClO₄ and [<b>2</b>]­ClO₄, because of the varying binding modes of partially deprotonated HL^–. …”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units ‌ Wolfram W. Seidel (1261020)

“…The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. …”

Synthesis and Characterization of Dimetallic Oxorhenium(V) and Dioxorhenium(VII) Compounds, and a Study of Stoichiometric and Catalytic Reactions ‌ James H. Espenson (2536300)

“…They, too, have similar Re₂S₂ cores that involve donor atoms from two of the dithiolate ligands; the third dithiolate chelates one of the rhenium atoms. …”

Contrasting Thermal and Photochemical Intramolecular Coupling in Alkynylphosphine Platinum(II) Complexes ‌ Ana García (2440420)

“…Thus, while under photochemical conditions complex <b>6</b> yields selectively [Pt]{Ph₂PC(Ph)C(Ph)PPhH}, <b>7</b>, by a ligand rearrangement coupling process involving activation of a P−C(Ph) bond, the regioisomer [Pt]{Ph₂PC(H)C(Ph)PPh₂}, <b>8</b>, is generated by a thermal activation of the P−H bond.…”

Ligand-Induced and Reductively Induced Alkyne−Isocyanide Coupling Reactions of [Mo(CNBu^t)₃(PhC⋮CPh)(η⁵-C₅Me₅)][BF₄... ‌ Christopher J. Adams (1847317)

“…A similar reaction of <b>4</b> with P(OMe)₃ generates [Mo{C(NHBu^t)C(Ph)C(Ph)CN}(CNBu^t){P(OMe)₃}(η⁵-C₅Me₅)][BF₄], <b>5</b>, involving the same coupling and elimination pattern. …”

Bis‑<i>N</i>‑Heterocyclic Carbene (NHC) Stabilized η⁶‑Arene Iron(0) Complexes: Synthesis, Structure, Reactivity, and Catalytic Activity ‌ Burgert Blom (1345701)

“…Complex <b>2</b> is unstable in aromatic solvents and forms, <i>via</i> a novel synthetic transformation involving intramolecular reductive elimination and concomitant PMe₃ elimination, the Fe (0) arene complex [Fe­{(^DippC:)₂CH₂}­(η⁶-C₆D₆)] (<b>4-<i>d</i></b>_<b>6</b>) in C₆D<sub>6.…”

Synthesis and Structure of Intermediates in Copper-Catalyzed Alkylation of Diphenylphosphine ‌ Matthew F. Cain (2269663)

“…These observations are consistent with a proposed mechanism for catalytic P−C bond formation involving deprotonation of the cationic diphenylphosphine complex [Cu(triphos)(PHPh₂)][PF₆] (<b>12</b>) by NaOSiMe₃ to yield the phosphido complex Cu(triphos)(PPh₂) (<b>22</b>). …”

Rooted phylogenetic tree of 550 base pair E1 fragment produced from Bayesian analysis using BEAST. ‌ Isabel Fourie (11896234)

“…Phylogenetic analysis with strong posterior probability support was obtained as follows: the concatenated (ORF1 and ORF 2) and nsP region placed MIDV in its own complex as seen for analysis using nsP4, while analysis using the sP region placed MIDV within the SF complex as seen with analyses involving the E1 fragment (which forms part of the structural proteins) (Figs <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g003" target="_blank">3</a>, <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g004" target="_blank">4</a> and <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g005" target="_blank">5</a>). …”