P−C and C−C Bond Formation by Michael Addition in Platinum-Catalyzed Hydrophosphination and in the Stoichiometric Reactions of Platinum Phosphido Complexes with Activated Alkenes... od Corina Scriban (1989502)

“…Subsequent C−H bond formation involving the Pt−H and the carbanion would yield the product R₂PCH₂CH₂X (<b>3</b>) and regenerate the catalyst, while attack of the carbanion on another alkene would yield byproducts derived from more than one alkene, such as R₂P(CH₂CH(X))<i>_n</i>CH₂CH₂X (<b>7</b>). …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... od Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

New Insights into the Visible-Light-Induced DNA Cleavage Activity of Dipyridoquinoxaline Complexes of Bivalent 3d-Metal Ions od Mithun Roy (2090650)

“…The DNA cleavage reactions at visible light under aerobic conditions involve the formation of hydroxyl radical. The Co^II complex shows photocleavage of DNA under an argon atmosphere. …”

Nyamsuren, I., Mitchell, E., and Tsay, J. (April 27 - May 2, 2025), <i>Learning Sign Language with Real-Time Kinematic Feedback</i> [Poster Presentation]. The Annual Meeting of the... od Indranil Nyamsuren (21498833)

“…At the baseline stage, participants attempted to guess the signs for 24 letters of the ASL alphabet without any cues (we excluded the letters J and Z because signs that involve movement are more difficult to recognize). …”

Valve Sparing in Type A Aortic Dissection od Vishal Shah (5651)

“…<br><br>Given the extensive involvement of the aortic root and the age of the patient, a decision was made to perform a valve sparing surgery. …”

Directed Synthesis of the Triangular Mixed-Metal Cluster H₂RhRe₂Cp*(CO)₉: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of C... od Shih-Huang Huang (2148001)

“…On the basis of the first-order rate constants and the Eyring activation parameters (Δ<i>H</i>^⧧ = 25.0(8) kcal/mol; Δ<i>S</i>^⧧ = −2.6(3) eu), a rate-limiting step involving a polyhedral opening of <b>4</b> is supported. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... od Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Structural Diversity in Supramolecular Complexes of MCl₃ (M = As, Sb, Bi) with Constrained Thio- and Seleno-Ether Ligands od William Levason (1275612)

“…[BiCl₃{<i>o</i>-C₆H₄(SeMe)₂}] comprises distorted square pyramidal units involving pyramidal BiCl₃ primary coordination and a weakly chelating diselenoether ligand, and assembled into infinite chains through long bridging Bi···Cl interactions via all three Clʼs. …”

Single-Molecule Magnets:  Two-Electron Reduced Version of a Mn₁₂ Complex and Environmental Influences on the Magnetization Relaxation of (PPh₄)₂[Mn... od Monica Soler (2337547)

“…Complexes <b>4a</b> and <b>4b</b> give resolvable frequency-dependent out-of-phase (χ_M‘ ‘) signals in AC susceptibility studies resulting from the magnetization relaxation of SMMs. …”

Preparation, Structure, and Properties of the Corner-Shared Double Cubes [Mo₆HgQ₈(H₂O)₁₈]⁸⁺ (Q = S, Se) and Tungsten Analogue... od Vladimir P. Fedin (1491637)

“…Furthermore, on dilution of column-purified [Mo₆HgS₈(H₂O)₁₈]⁸⁺, Beer's law is not obeyed and equilibria involving 2[Mo₃S₄(H₂O)₉]⁴⁺ are apparent. …”

Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenid... od Noorjahan Begum (2388037)

“…Compounds <b>3</b>, <b>6</b>, <b>7</b>, and <b>10</b> exhibit restricted fluxional behavior involving the μ-EPh moieties.…”

Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenid... od Noorjahan Begum (2388037)

“…Compounds <b>3</b>, <b>6</b>, <b>7</b>, and <b>10</b> exhibit restricted fluxional behavior involving the μ-EPh moieties.…”

Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenid... od Noorjahan Begum (2388037)

“…Compounds <b>3</b>, <b>6</b>, <b>7</b>, and <b>10</b> exhibit restricted fluxional behavior involving the μ-EPh moieties.…”

Reactions of Diamidonaphthalene-Bridged Diiridium Tetrahydrides with Alkynes:  Hydrogenation, Vinylidene Formation, and Catalytic C−C Coupling od M. Victoria Jiménez (2457487)

“…A similar reaction with bis(trimethylsilyl)acetylene forms the bis-vinylidene complex [Ir₂{μ-1,8-(NH)₂C₁₀H₆){CC(SiMe₃)₂}₂(P<i>i</i>Pr₃)₂] (<b>11</b>) together with 2 equiv of H₂CC(SiMe₃)₂. …”

Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenid... od Noorjahan Begum (2388037)

“…Compounds <b>3</b>, <b>6</b>, <b>7</b>, and <b>10</b> exhibit restricted fluxional behavior involving the μ-EPh moieties.…”

Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenid... od Noorjahan Begum (2388037)

“…Compounds <b>3</b>, <b>6</b>, <b>7</b>, and <b>10</b> exhibit restricted fluxional behavior involving the μ-EPh moieties.…”

Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenid... od Noorjahan Begum (2388037)

“…Compounds <b>3</b>, <b>6</b>, <b>7</b>, and <b>10</b> exhibit restricted fluxional behavior involving the μ-EPh moieties.…”

Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers That Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H₂meppp = <i>meso</i>-1,3-Bis[... od Bunsho Kure (1536136)

“…The reaction is assumed to involve an alkenyl complex, [Ni­(μ-meppp)­RhCp*­(CHCHPh)]­NO₃ (<b>9a</b>), formed through an insertion of phenylacetylene into the metal–hydride bond. …”

Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers That Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H₂meppp = <i>meso</i>-1,3-Bis[... od Bunsho Kure (1536136)

“…The reaction is assumed to involve an alkenyl complex, [Ni­(μ-meppp)­RhCp*­(CHCHPh)]­NO₃ (<b>9a</b>), formed through an insertion of phenylacetylene into the metal–hydride bond. …”

[Mn₁₂O₁₂(OMe)₂(O₂CPh)₁₆(H₂O)₂]^2- Single-Molecule Magnets and Other Manganese Compounds from... od Anastasios J. Tasiopoulos (1397299)

“…A new synthetic procedure has been developed in Mn cluster chemistry involving reductive aggregation of permanganate (MnO₄^-) ions in MeOH in the presence of benzoic acid, and the first products from its use are described. …”