Structural, Electrochemical, and Spectroscopic Investigation of Acetate Bridged Dinuclear Tetrakis-Schiff Base Macrocycles of Mn and Zn di Subhadeep Kal (1720603)

“...The electrochemical and spectroscopic analysis of these complexes will aid in future studies involving electrocatalytic processes with related dinuclear macrocycles....”

The Dinuclear Zn(II) Complex Catalyzed Cyclization of a Series of 2-Hydroxypropyl Aryl Phosphate RNA Models:  Progressive Change in Mechanism from Rate-Limiting P−O Bond Cleavage t... di Shannon E. Bunn (2438131)

“...The data are analyzed in terms of a multistep process whereby a first formed complex rearranges to a reactive complex with a doubly activated phosphate coordinated to both metal ions. ...”

Reversible Switching of the Coordination Modes of a Pyridine-Functionalized Quinonoid Zwitterion; Its Di- and Tetranuclear Palladium Complexes di Alessio Ghisolfi (1588846)

“...This switch modifies the extent of π-delocalization involving the potentially antiaromatic quinonoid moiety and is accompanied by a significant color change, from red in <b>3</b> to green in <b>4</b>. ...”

Organometallic Complexes of Scandium and Yttrium Supported by a Bulky Salicylaldimine Ligand di David J. H. Emslie (1425715)

“...These compounds are highly thermally stable, decomposing at temperatures above 140 °C via a pathway involving metalation of one of the N-aryl isopropyl methyl groups. ...”

Hormone-independent, EcR-mediated endoreplication of SC DNA is stimulated by mating. di Aaron Leiblich (3211392)

“...(F) Proposed model explaining the different forms of hormone-dependent and hormone-independent, EcR-mediated SC growth in virgin and mated males. ...”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units di Wolfram W. Seidel (1261020)

“...The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. ...”

[(Cp−CMe₂−Flu)₂Ln]^-[Li(ether)<i>_n</i>]⁺ (Ln = Y, La):  Complexes with Unusual Coordination Modes of the Fluorenyl Ligand and... di Evgueni Kirillov (1425814)

“...The fluorenyl ligands in <b>2</b> show an unprecedented η¹ bonding mode and a rare η³ bonding mode involving, respectively, a carbon atom of a phenyl ring and the bridgehead carbon atom of the central ring and the two adjacent carbon atoms of one six-membered ring. ...”

Revelation of Varying Coordination Modes and Noninnocence of Deprotonated 2,2′-Bipyridine-3,3′-diol in {Os(bpy)₂} Frameworks di Prabir Ghosh (1625659)

“...The reaction of 2,2′-bipyridine-3,3′-diol (H₂L) and <i>cis</i>-Os^II(bpy)₂­Cl₂ (bpy = 2,2′-bipyridine) results in isomeric forms of [Os^II(bpy)₂(HL^–)]­ClO₄, [<b>1</b>]­ClO₄ and [<b>2</b>]­ClO₄, because of the varying binding modes of partially deprotonated HL^–. ...”

On the Prospects of Polynuclear Complexes with Acetylenedithiolate Bridging Units di Wolfram W. Seidel (1261020)

“...The very intense visible absorptions involve essential d orbital contributions of the central metal, while the redox activity is primarily attributed to the alkyne complex moiety. ...”

Synthesis and Characterization of Dimetallic Oxorhenium(V) and Dioxorhenium(VII) Compounds, and a Study of Stoichiometric and Catalytic Reactions di James H. Espenson (2536300)

“...They, too, have similar Re₂S₂ cores that involve donor atoms from two of the dithiolate ligands; the third dithiolate chelates one of the rhenium atoms. ...”

Contrasting Thermal and Photochemical Intramolecular Coupling in Alkynylphosphine Platinum(II) Complexes di Ana García (2440420)

“...Thus, while under photochemical conditions complex <b>6</b> yields selectively [Pt]{Ph₂PC(Ph)C(Ph)PPhH}, <b>7</b>, by a ligand rearrangement coupling process involving activation of a P−C(Ph) bond, the regioisomer [Pt]{Ph₂PC(H)C(Ph)PPh₂}, <b>8</b>, is generated by a thermal activation of the P−H bond....”

Ligand-Induced and Reductively Induced Alkyne−Isocyanide Coupling Reactions of [Mo(CNBu^t)₃(PhC⋮CPh)(η⁵-C₅Me₅)][BF₄... di Christopher J. Adams (1847317)

“...A similar reaction of <b>4</b> with P(OMe)₃ generates [Mo{C(NHBu^t)C(Ph)C(Ph)CN}(CNBu^t){P(OMe)₃}(η⁵-C₅Me₅)][BF₄], <b>5</b>, involving the same coupling and elimination pattern. ...”

Bis‑<i>N</i>‑Heterocyclic Carbene (NHC) Stabilized η⁶‑Arene Iron(0) Complexes: Synthesis, Structure, Reactivity, and Catalytic Activity di Burgert Blom (1345701)

“...Complex <b>2</b> is unstable in aromatic solvents and forms, <i>via</i> a novel synthetic transformation involving intramolecular reductive elimination and concomitant PMe₃ elimination, the Fe (0) arene complex [Fe­{(^DippC:)₂CH₂}­(η⁶-C₆D₆)] (<b>4-<i>d</i></b>_<b>6</b>) in C₆D<sub>6....”

Synthesis and Structure of Intermediates in Copper-Catalyzed Alkylation of Diphenylphosphine di Matthew F. Cain (2269663)

“...These observations are consistent with a proposed mechanism for catalytic P−C bond formation involving deprotonation of the cationic diphenylphosphine complex [Cu(triphos)(PHPh₂)][PF₆] (<b>12</b>) by NaOSiMe₃ to yield the phosphido complex Cu(triphos)(PPh₂) (<b>22</b>). ...”

Synthesis, Characterization, and Chiral Behavior of S-Bridged Co^IIIPt^IICo^III Trinuclear Complexes Composed of Bis(thiolato)-Type Octahedral Units <... di Hirokazu Honda (2964768)

“...Complex [<b>1</b>]⁴⁺ formed both racemic (ΔΔ/ΛΛ) and meso (ΔΛ) forms, which were separated and optically resolved by cation-exchange column chromatography. ...”

Rooted phylogenetic tree of 550 base pair E1 fragment produced from Bayesian analysis using BEAST. di Isabel Fourie (11896234)

“...Phylogenetic analysis with strong posterior probability support was obtained as follows: the concatenated (ORF1 and ORF 2) and nsP region placed MIDV in its own complex as seen for analysis using nsP4, while analysis using the sP region placed MIDV within the SF complex as seen with analyses involving the E1 fragment (which forms part of the structural proteins) (Figs <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g003" target="_blank">3</a>, <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g004" target="_blank">4</a> and <a href="http://www.plosntds.org/article/info:doi/10.1371/journal.pntd.0010020#pntd.0010020.g005" target="_blank">5</a>). ...”

Tuning the Inclusion Properties and Solid-State Reactivity of Second Sphere Adducts Using Conformationally Flexible Bidentate Ligands di Fang Guo (105824)

“...We demonstrate that some of the second sphere adducts are dynamic, showing reversible guest release/uptake involving crystalline-to-amorphous-to-crystalline phase transformations. ...”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... di Sridhar A. Lahankar (1294842)

“...Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. ...”

Near-isotropic, reconstructed volume electron microscopy (FIB-SEM) of mouse dorsal striatum (jrc_mus-dorsal-striatum) di CellMap Project Team (14322654)

“...Here, we have used focused ion beam-scanning electron microscopy to generate 3D reconstructions of intracellular organelles and their membrane appositions involving the ER (distance ≤30 nm) in different neuronal compartments. ...”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... di Sridhar A. Lahankar (1294842)

“...Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. ...”