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27961
New Amine-Templated Zinc Phosphates with a Temperature-Induced Increase of Structural Dimensionality
Published 2005“…The complete hydrogen-bond scheme is resolved for these new compounds and reveals some interesting phenomena, for example, a hydrogen shared between two phosphate groups in <b>AU</b><b>-</b><b>II</b>, thereby forming H<sub>0.5</sub>PO<sub>4</sub> groups. …”
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27962
Overview of known molecular pathways of ATRX.
Published 2025“…ATRX helps sequester TERRA and participates in resolving these secondary structures, although its precise mechanism of action remains to be fully elucidated. …”
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27963
Machine learning to identify pairwise interactions between specific IgE antibodies and their association with asthma: A cross-sectional analysis within a population-based birth coh...
Published 2018“…Of the 44 components included in the model, 33 grouped in seven clusters (C.sIgE-1–7), and the remaining 11 formed singleton clusters. Cluster membership mapped closely to the structural homology of proteins and/or their biological source. …”
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27964
Synthesis and Reactivity of Titanium Hydrazido Complexes Supported by Diamido-Ether Ligands
Published 2013“…With Ar′NCS the [2+2] cycloaddition product Ti(N<sub>2</sub>O){N(NPh<sub>2</sub>)C(NAr′)S}(py) was obtained, and with Ar′NCSe a mixture was formed including Ti<sub>2</sub>(N<sub>2</sub>O)<sub>2</sub>(μ-Se)<sub>2</sub>. …”
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27965
Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η<sup>3</sup>(<i>BCC</i>)-Triarylborane Coordination
Published 2008“…By contrast, the TXPB ligand in <b>2</b> is bound to palladium not only via the phosphine and thioether donors but also through a Pd-(η<sup>3</sup>-BAr<sub>3</sub>) linkage involving boron and the <i>ipso</i>- and <i>ortho</i>-carbon atoms of one <i>B</i>-phenyl ring. …”
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27966
C−C and C−N Coupling Reactions of an Imidotitanium Complex with Isocyanides
Published 2000“…These products are thought to be formed in a reaction sequence involving intermediates that are analogous to the stable complexes <b>2</b> and <b>3a</b>−<b>h</b>. …”
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27967
Assembly of Soft Metal Complexes of an O<sub>4</sub>S<sub>2</sub>‑Macrocycle Displaying Endocyclic Monomer, Dumbbell-Like Dimer, and Endo-/Exocyclic Polymer Structures
Published 2012“…The X-ray structures of seven complexes (<b>1</b>–<b>7</b>) have been determined, and a range of structural types and coordination modes, including discrete to continuous forms, mono- to multinuclear, and endo- to exocyclic structures involving M–S bonds, are presented. …”
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27968
Influence of the Ligand Alkyl Chain Length on the Solubility, Aqueous Speciation, and Kinetics of Substitution Reactions of Water-Soluble M<sub>3</sub>S<sub>4</sub> (M = Mo, W) Clu...
Published 2013“…On the basis of the kinetic results, a mechanism with two parallel reaction pathways involving water and OH<sup>–</sup> attacks is proposed for the formal substitution of halides by hydroxo ligands. …”
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27969
Distinct GluN1 and GluN2 Structural Determinants for Subunit-Selective Positive Allosteric Modulation of <i>N</i>‑Methyl‑d‑aspartate Receptors
Published 2020“…Several neurological disorders may involve NMDAR hypofunction, which has driven therapeutic interest in positive allosteric modulators (PAMs) of NMDAR function. …”
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27970
Mononuclear Titanium(IV)−Citrate Complexes from Aqueous Solutions: pH-Specific Synthesis and Structural and Spectroscopic Studies in Relevance to Aqueous Titanium(IV)−Citrate Spec...
Published 2005“…In an effort to comprehend the involvement of titanium in requisite biological interactions with physiological ligands, synthetic efforts were launched targeting aqueous soluble species of Ti(IV). …”
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27971
Trinuclear Nickel Complexes with Triplesalen Ligands: Simultaneous Occurrence of Mixed Valence and Valence Tautomerism in the Oxidized Species
Published 2005“…Thus, these oxidized forms exhibit the phenomena of valence tautomerism and mixed valence simultaneously. …”
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27972
Alkylation, Cation Formation, and Insertion Reactions in Titanium Tris(ketimide) Complexes
Published 2007“…Above 60 °C, C<sub>6</sub>F<sub>5</sub> is transferred to the metal center and Ti(NC<sup>t</sup>Bu<sub>2</sub>)<sub>3</sub>(C<sub>6</sub>F<sub>5</sub>) (<b>9</b>) forms. This compound participates in a dynamic process in solution involving Ti···F interactions. …”
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27973
Trinuclear Nickel Complexes with Triplesalen Ligands: Simultaneous Occurrence of Mixed Valence and Valence Tautomerism in the Oxidized Species
Published 2005“…Thus, these oxidized forms exhibit the phenomena of valence tautomerism and mixed valence simultaneously. …”
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27974
Study selection flow chart.
Published 2025“…</p><p>Methods</p><p>Studies will be considered eligible if they are randomized controlled trials (RCTs), quasi-experimental studies, and Observational studies (cohort, case-control, cross-sectional studies) involving women and couples with infertility problems and living in a LMIC who received a psychosocial intervention to improve marital intimacy, sexual satisfaction, and QoL. …”
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27975
Network assessment of demethylation treatment in melanoma: Differential transcriptome-methylome and antigen profile signatures
Published 2018“…Overall, the non-metastatic SKMEL-2 map reveals post-treatment re-activation of a richer pathway landscape, involving cadherins and integrins as signatures of cell adhesion and proliferation. …”
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27976
Data supporting the figures and supplementary figures and tables in the published article: Suppression of FOXM1 activities and breast cancer growth in vitro and in vivo by a new cl...
Published 2019“…</div><div><br></div><div><b>Study approval:</b> All experiments involving animals were conducted in accordance with National Institutes of Health (NIH) standards for the care and use of animals, with protocols approved by the University of Illinois IACUC.…”
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27977
Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η<sup>3</sup>(<i>BCC</i>)-Triarylborane Coordination
Published 2008“…By contrast, the TXPB ligand in <b>2</b> is bound to palladium not only via the phosphine and thioether donors but also through a Pd-(η<sup>3</sup>-BAr<sub>3</sub>) linkage involving boron and the <i>ipso</i>- and <i>ortho</i>-carbon atoms of one <i>B</i>-phenyl ring. …”
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27978
Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η<sup>3</sup>(<i>BCC</i>)-Triarylborane Coordination
Published 2008“…By contrast, the TXPB ligand in <b>2</b> is bound to palladium not only via the phosphine and thioether donors but also through a Pd-(η<sup>3</sup>-BAr<sub>3</sub>) linkage involving boron and the <i>ipso</i>- and <i>ortho</i>-carbon atoms of one <i>B</i>-phenyl ring. …”
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27979
Challenges in water supply systems and service delivery in the Mankweng Cluster : perspectives from households, ward councillors, and the Polokwane Municipality
Published 2025“…Through a mixed-methods approach involving questionnaires distributed to 200 households across seven wards and interviews with municipal officials and ward councillors, the study found that most residents are forced to rely on unsafe water sources like rivers and ponds, thereby endangering public health. …”
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27980
Induction of autophagy through CLEC4E in combination with TLR4: an innovative strategy to restrict the survival of <i>Mycobacterium tuberculosis</i>
Published 2019“…This study suggests a unique immunotherapeutic approach involving CLEC4E in conjunction with TLR4 to restrict the survival of <i>Mtb</i> through autophagy.…”