Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers That Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H₂meppp = <i>meso</i>-1,3-Bis[... 著者: Bunsho Kure (1536136)

“…The reaction is assumed to involve an alkenyl complex, [Ni­(μ-meppp)­RhCp*­(CHCHPh)]­NO₃ (<b>9a</b>), formed through an insertion of phenylacetylene into the metal–hydride bond. …”

Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers That Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H₂meppp = <i>meso</i>-1,3-Bis[... 著者: Bunsho Kure (1536136)

“…The reaction is assumed to involve an alkenyl complex, [Ni­(μ-meppp)­RhCp*­(CHCHPh)]­NO₃ (<b>9a</b>), formed through an insertion of phenylacetylene into the metal–hydride bond. …”

Creative methods and practices to mobilising public health knowledge webinar 著者: Joe Langley (2382391)

“…</p><p dir="ltr">In the field of public health, mobilising evidence and other forms of knowledge is essential to developing effective, equitable, and sustainable interventions. …”

Stereoselectivity in the Formation of Metallomacrocycles from [Mo(NO){HB(3,5-Me₂C₃HN₂)₃}I₂] and Ditopic Proligands:  The X-ra... 著者: Ferida S. McQuillan (2962425)

“…These binuclear complexes are formed under kinetic control so that <i>syn</i>-[Mo(NO)(tp*){1,4-(OCH₂)₂C₆H₄}]₂, <b>2s</b>, forms more rapidly than <i>anti</i>-[Mo(NO)(tp*){1,4-(OCH₂)₂C₆H₄}]₂, <b>2a</b>, but in lower yield. …”

New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis 著者: Masanari Hirahara (1558075)

“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b>_<b>2</b><b>(OH)­(OH</b>_<b>2</b><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru^III–OH:Ru^III–OH state species as a resting state. …”

New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis 著者: Masanari Hirahara (1558075)

“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b>_<b>2</b><b>(OH)­(OH</b>_<b>2</b><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru^III–OH:Ru^III–OH state species as a resting state. …”

New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis 著者: Masanari Hirahara (1558075)

“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b>_<b>2</b><b>(OH)­(OH</b>_<b>2</b><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru^III–OH:Ru^III–OH state species as a resting state. …”

Mixed-Metal Cluster Chemistry. 30. Syntheses and Optical Limiting Properties of Cluster-Containing Oligo- and Polyurethanes 著者: Michael D. Randles (2034709)

“…Some insight into the mechanism by which these clusters function as optical limiters has been gleaned from complementary pump−probe studies, with their behavior consistent with a fast nonlinear absorption process followed by reverse saturable absorption involving metastable excited states of greater than nanosecond lifetime.…”

Eh!woza Learner Doccies 著者: Anastasia Koch (9420299)

“…</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. …”

W₂Cl₄(NR₂)₂(PR‘₃)₂ Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and... 著者: F. Albert Cotton (1781341)

“…The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. …”

Unusual [Pt{κ²(<i>C</i>,<i>N</i>)}]⁺ → [Pt{κ²(<i>N</i>,<i>N</i>)}]⁺ Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>... 著者: Rishabh Ujjval (9454247)

“…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt­{κ²(<i>C</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt­{κ²(<i>N</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>16</b>′), is a kinetically controlled product.…”

Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025) 著者: Thomas Gernon (11046150)

“…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”

17- and 19-Electron Complexes [Fe^III(η⁵-C₅R₅)(S₂CNMe₂)L]^<i>n</i>+ (<i>n</i> = 1, 0):  Electronic Struct... 著者: Marie-Hélène Delville-Desbois (2995521)

“…The cyclic voltammogram of <b>9⁺PF₆^-</b> under continuous scanning for the monoelectronic reduction and the two monoelectronic reductions showed the decrease of the waves of <b>9⁺PF₆^-</b> and the concomitant increase of those due to the partially decoordinated dtc complexes formed upon reduction. This permits an interpretation of the CV in terms of a triple-square scheme involving <b>9</b>^+/<b>0</b>/-, <b>9‘</b>^+/<b>0</b>/-, and solvent (DMF) adducts in 18- and 19e states.…”