Anion-Directed Synthesis of Metal−Organic Frameworks Based on 2-Picolinate Cu(II) Complexes:  A Ferromagnetic Alternating Chain and Two Unprecedented Ferromagnetic Fish Backbone Ch... av Chaitali Biswas (2284117)

“…The structural analyses reveal that complexes <b>1</b> and <b>2</b> are constructed by “fish backbone” chains through <i>syn</i><i>−</i><i>anti</i> (equatorial−equatorial) carboxylate bridges, which are linked to one another by <i>syn</i><i>−</i><i>anti</i> (equatorial−axial) carboxylate bridges, giving rise to a rectangular grid-like two-dimensional net. Complex <b>3</b> is formed by alternating chains of <i>syn</i><i>−</i><i>anti</i> carboxylate-bridged copper(II) atoms, which are linked together by strong H bonds involving coordinated nitrate ions and water molecules and uncoordinated oxygen atoms from carboxylate groups. …”

Data_Sheet_1_Investigating Abiotic and Biotic Mechanisms of Pyrite Reduction.PDF av Rachel L. Spietz (11822615)

“…However, the mechanism of FeS₂ mineral reduction and the forms of Fe and S assimilated by methanogens remained unclear. …”

Anion-Directed Synthesis of Metal−Organic Frameworks Based on 2-Picolinate Cu(II) Complexes:  A Ferromagnetic Alternating Chain and Two Unprecedented Ferromagnetic Fish Backbone Ch... av Chaitali Biswas (2284117)

“…The structural analyses reveal that complexes <b>1</b> and <b>2</b> are constructed by “fish backbone” chains through <i>syn</i><i>−</i><i>anti</i> (equatorial−equatorial) carboxylate bridges, which are linked to one another by <i>syn</i><i>−</i><i>anti</i> (equatorial−axial) carboxylate bridges, giving rise to a rectangular grid-like two-dimensional net. Complex <b>3</b> is formed by alternating chains of <i>syn</i><i>−</i><i>anti</i> carboxylate-bridged copper(II) atoms, which are linked together by strong H bonds involving coordinated nitrate ions and water molecules and uncoordinated oxygen atoms from carboxylate groups. …”

An Experimental and Theoretical Investigation of the Carbon Dioxide Insertion Process into the Tungsten−Nitrogen Bond of an Anionic W(0) Complex av Donald J. Darensbourg (1317624)

“…Finally, both experimental and theoretical studies were inconclusive with regard to identifying reaction intermediates during the CO₂ insertion pathway which involve prior interactions of CO₂ at the amido nitrogen center.…”

Unprecedented Tris-Phosphido-Bridged Triangular Clusters with 42 Valence Electrons. Chemical, Electrochemical and Computational Studies of their Formation and Stability av Tiziana Funaioli (249029)

“…Another piece of information is that, together with the fully oxidized product Pt₃(μ-PBu^<i>t</i>₂)₃I₃, the transient 44e^– species [Pt₃(μ-PBu^<i>t</i>₂)₃(CO)₃]⁺ is formed in the early steps of the reaction. In order to extract detailed information on the formation pathway, involving both terminal ligand substitutions and electron transfer processes, a DFT investigation has been performed and all the possible intermediates have been defined together with their associated energy costs. …”

Anion-Directed Synthesis of Metal−Organic Frameworks Based on 2-Picolinate Cu(II) Complexes:  A Ferromagnetic Alternating Chain and Two Unprecedented Ferromagnetic Fish Backbone Ch... av Chaitali Biswas (2284117)

“…The structural analyses reveal that complexes <b>1</b> and <b>2</b> are constructed by “fish backbone” chains through <i>syn</i><i>−</i><i>anti</i> (equatorial−equatorial) carboxylate bridges, which are linked to one another by <i>syn</i><i>−</i><i>anti</i> (equatorial−axial) carboxylate bridges, giving rise to a rectangular grid-like two-dimensional net. Complex <b>3</b> is formed by alternating chains of <i>syn</i><i>−</i><i>anti</i> carboxylate-bridged copper(II) atoms, which are linked together by strong H bonds involving coordinated nitrate ions and water molecules and uncoordinated oxygen atoms from carboxylate groups. …”

The Intronic Long Noncoding RNA <i>ANRASSF1</i> Recruits PRC2 to the <i>RASSF1A</i> Promoter, Reducing the Expression of <i>RASSF1A</i> and Increasing Cell Proliferation av Felipe C. Beckedorff (449218)

“…<i>RASSF1A</i> expression is regulated through epigenetic events involving the polycomb repressive complex 2 (PRC2); however, the molecular mechanisms modulating the recruitment of this epigenetic modifier to the <i>RASSF1</i> locus remain largely unknown. …”

Table_1_Investigating Abiotic and Biotic Mechanisms of Pyrite Reduction.XLSX av Rachel L. Spietz (11822615)

“…However, the mechanism of FeS₂ mineral reduction and the forms of Fe and S assimilated by methanogens remained unclear. …”

Palladium-Catalyzed Hydrohalogenation of 1,6-Enynes: Hydrogen Halide Salts and Alkyl Halides as Convenient HX Surrogates av David A. Petrone (1520437)

“…Experimental and computational studies support a reaction mechanism involving a crucial <i>E</i>-to-<i>Z</i> vinyl–Pd isomerization and a carbon–halogen bond-forming reductive elimination. …”

Palladium-Catalyzed Hydrohalogenation of 1,6-Enynes: Hydrogen Halide Salts and Alkyl Halides as Convenient HX Surrogates av David A. Petrone (1520437)

“…Experimental and computational studies support a reaction mechanism involving a crucial <i>E</i>-to-<i>Z</i> vinyl–Pd isomerization and a carbon–halogen bond-forming reductive elimination. …”

Image_1_Autophagy Hijacking in PBMC From COVID-19 Patients Results in Lymphopenia.jpeg av Cristiana Barbati (147784)

“…Recent findings suggest an involvement of this process in severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) infection. …”

DataSheet_1_Autophagy Hijacking in PBMC From COVID-19 Patients Results in Lymphopenia.pdf av Cristiana Barbati (147784)

“…Recent findings suggest an involvement of this process in severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) infection. …”

Supramolecular Dual Polypeptides Induced Tubulin Aggregation for Synergistic Cancer Theranostics av Mian Tang (12480493)

“…Herein, we construct a supra-biomacromolecular nanosystem involving microtubules, cell-permeable porphyrins, and antimitotic peptide-decorated permethyl-β-cyclodextrins for promoting cell apoptosis in a cooperative manner. …”

Palladium-Catalyzed Hydrohalogenation of 1,6-Enynes: Hydrogen Halide Salts and Alkyl Halides as Convenient HX Surrogates av David A. Petrone (1520437)

“…Experimental and computational studies support a reaction mechanism involving a crucial <i>E</i>-to-<i>Z</i> vinyl–Pd isomerization and a carbon–halogen bond-forming reductive elimination. …”

Practical and Highly Selective Sulfur Ylide-Mediated Asymmetric Epoxidations and Aziridinations Using a Cheap and Readily Available Chiral Sulfide: Extensive Studies To Map Out Sco... av Ona Illa (1536673)

“…The chiral sulfide, isothiocineole, has been synthesized in one step from elemental sulfur, γ-terpinene, and limonene in 61% yield. A mechanism involving radical intermediates for this reaction is proposed based on experimental evidence. …”

Models for Catalytic Mechanisms of Mammalian MsrB Enzymes av Hwa-Young Kim (12128)

“…A resulting selenenic acid intermediate of selenoprotein MsrB1, which is not reducible by Trx, then forms a selenenylsulfide bond with resolving Cys4. …”

Data_Sheet_1_Characterizing the Binding Sites for GK Domain of DLG1 and DLG4 via Molecular Dynamics Simulation.PDF av Hongwei Li (17402)

“…The GK domain of DLGs has evolved into a protein–protein interaction module that could bind with kinds of proteins to regulate diverse cellular functions. …”

Gold-Catalyzed Intramolecular Allylic Amination of 2-Tosylaminophenylprop-1-en-3-ols. A Concise Synthesis of (±)-Angustureine av Prasath Kothandaraman (2047204)

“…The mechanism is suggested to involve activation of the alcohol substrate by the AuCl₃/AgSbF₆ catalyst. …”

Schematic representation of a proposed model depicting functional influences of genetic variations in <i>BMPR1B</i> 3′UTR on endometriosis development. av Cherry Yin-Yi Chang (493833)

“…<p>Mature miRNAs including miR-125b are produced by several processing steps where the microprocessor complex (Drosha/DGCR8), exportin 5 and Dicer/TRBP/PACT complex have been known to involve in. The resulting miR-125b forms a RISC complex with Ago and silences BMPR1B gene by binding to the complementary sequence in <i>BMPR1B</i> 3′UTR. …”

Data_Sheet_1_Guidelines to Facilitate Human-Wildlife Interactions in Conservation Translocations.docx av Adriana Consorte-McCrea (12089147)

“…When the human dimensions are included there is greater possibility of community involvement, peers' acceptance and support from various interest groups and avoidance of conflict situations. …”