Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic... Bằng Kyle G. Lewis (1355400)

“…It is found that Werner complexes based upon the D₃ symmetric chiral trication [Co­(en)₃]³⁺ (en = 1,2-ethylenediamine), which features an earth abundant metal and cheap ligand type, and was among the first inorganic compounds resolved into enantiomers 103 years ago, catalyze a valuable carbon–carbon bond forming reaction, the Michael addition of malonate esters to nitroalkenes, in high enantioselectivities and without requiring inert atmosphere conditions. …”

Supporting data for PhD thesis: Advancing Protein Chemical Synthesis: Knorr Pyrazole Synthesis Mediated Salicylaldehyde Esters Regeneration In TIM-1 Synthesis and Prior Disulfide B... Bằng Xiaolin Cheng (11147973)

“…To overcome this challenge, we developed a new strategy involving the precise formation of disulfide bonds prior to refolding, thereby eliminating the usage of redox systems and ensuring the acquisition of high-fidelity native disulfide arrangement. …”

Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic... Bằng Kyle G. Lewis (1355400)

“…It is found that Werner complexes based upon the D₃ symmetric chiral trication [Co­(en)₃]³⁺ (en = 1,2-ethylenediamine), which features an earth abundant metal and cheap ligand type, and was among the first inorganic compounds resolved into enantiomers 103 years ago, catalyze a valuable carbon–carbon bond forming reaction, the Michael addition of malonate esters to nitroalkenes, in high enantioselectivities and without requiring inert atmosphere conditions. …”

Synthesis, Crystal Structure, Aqueous Speciation, and Kinetics of Substitution Reactions in a Water-Soluble Mo₃S₄ Cluster Bearing Hydroxymethyl Diphosphine Li... Bằng Andrés G. Algarra (2478166)

“…However, whereas the first two steps involve the opening of the chelate rings formed with the alkoxo groups of the dhmpe ligands, the third one corresponds to the substitution of the coordinated water molecule. …”

Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic... Bằng Kyle G. Lewis (1355400)

“…It is found that Werner complexes based upon the D₃ symmetric chiral trication [Co­(en)₃]³⁺ (en = 1,2-ethylenediamine), which features an earth abundant metal and cheap ligand type, and was among the first inorganic compounds resolved into enantiomers 103 years ago, catalyze a valuable carbon–carbon bond forming reaction, the Michael addition of malonate esters to nitroalkenes, in high enantioselectivities and without requiring inert atmosphere conditions. …”

Synthesis and Structural Characterization of an Unprecedented Nonmetal Cation Polyborate Salt Containing Two Different “Isolated” Polyborate Anions: [H₂en]₂[B... Bằng Michael A. Beckett (129337)

“…The structure is templated by the cations with the anions forming a supramolecular H-bonded network, augmented by additional H-bonds involving the waters of crystallization and the cations.…”

Two Novel Nanoporous Supramolecular Architectures Based on Copper(I) Coordination Polymers with Uniform (8, 3) and (8²10) Nets:  In Situ Formation of Tetrazolate Ligands... Bằng Tao Wu (16763)

“…The hydro/solvothermal reactions of Cu(I)/Cu(II) salt, NaN₃, and acetonitrile in water or methanol yield two noninterpenetrated supramolecular networks containing 1D hexagonal and square nanochannels, {[Cu(Mtta)]·0.17H₂O}<i>_n</i>(<b>1</b>) and its pseudopolymorph [Cu(Mtta)]<i>_n</i> (<b>2</b>) (Mtta = 5-methyl tetrazolate), involving ligand in-situ formation by cycloaddition of nitriles and azides. …”

Preferential Precipitation and Selective Separation of Rh(III) from Pd(II) and Pt(IV) Using 4‑Alkylanilines as Precipitants Bằng Kazuya Matsumoto (396968)

“…Here, a selective Rh separation method involving the precipitation of Rh from an HCl solution containing palladium (Pd), platinum (Pt), and Rh is reported. 4-Butylaniline and 4-hexylaniline were used as precipitants for Rh, and selective Rh precipitation was achieved at high HCl concentrations. …”

Efficient Synthesis of 3-Chloromethyl-2(5<i>H</i>)-furanones and 3-Chloromethyl- 5,6-dihydropyran-2-ones via the PdCl₂-Catalyzed Chlorocyclocarbonylation of 2,3- or 3,4-... Bằng Xin Cheng (179584)

“…A mild and efficient methodology involving PdCl₂-catalyzed chlorocyclocarbonylation of 2,3- or 3,4-allenols with CuCl₂ for the synthesis of 3-chloromethyl-2(5<i>H</i>)-furanones and 3-chloromethyl-5,6-dihydropyran-2-ones was developed. …”

Two Novel Nanoporous Supramolecular Architectures Based on Copper(I) Coordination Polymers with Uniform (8, 3) and (8²10) Nets:  In Situ Formation of Tetrazolate Ligands... Bằng Tao Wu (16763)

“…The hydro/solvothermal reactions of Cu(I)/Cu(II) salt, NaN₃, and acetonitrile in water or methanol yield two noninterpenetrated supramolecular networks containing 1D hexagonal and square nanochannels, {[Cu(Mtta)]·0.17H₂O}<i>_n</i>(<b>1</b>) and its pseudopolymorph [Cu(Mtta)]<i>_n</i> (<b>2</b>) (Mtta = 5-methyl tetrazolate), involving ligand in-situ formation by cycloaddition of nitriles and azides. …”

Generalisation experiments. Bằng Miguel Brun-Usan (8703918)

“…Similar experiments yield poor performances when cells have to evolve complex forms of plasticity (blue line below the green one, see main text). …”

Phosphinite-Ni(0) Mediated Formation of a Phosphide-Ni(II)-OCOOMe Species via Uncommon Metal–Ligand Cooperation Bằng Yeong-Eun Kim (1622962)

“…Thus, unanticipated metal–ligand cooperation involving a phosphide based ligand is reported.…”

Applications of multiple reaction monitoring targeted proteomics assays in human plasma Bằng Georgia Kontostathi (6709712)

“…Additionally, clinical aspects involving careful study design to address biomarker clinical use should also be considered.…”

Plasticity of the Nickel(II) Coordination Environment in Complexes with Hemilabile Phosphino Thioether Ligands Bằng Charles W. Machan (1417663)

“…A series of homoligated Ni(II) complexes formed from two phosphino thioether (P,S) chelating ligands has been synthesized and characterized. …”

Table_1_Computational Identification of the Proteins Associated With Quorum Sensing and Biofilm Formation in Mycobacterium tuberculosis.XLSX Bằng Shubhada R. Hegde (8344482)

“…Analysis of conservation across other biofilm-forming bacteria suggests that most of these genes are conserved in mycobacteria. …”

Two Families of Synthetic Peptides That Enhance Fibrin Turbidity and Delay Fibrinolysis by Different Mechanisms Bằng Leela Pandi (2359267)

“…When fibrin clots are formed in vitro in the presence of certain positively charged peptides, the turbidity is enhanced and fibrinolysis is delayed. …”

Longitudinal distribution of extreme pressures in a hydraulic jump downstream of a stepped spillway Bằng Carolina Kuhn Novakoski (6125498)

“…Thus, it was found that the pressure behavior is similar to that observed in studies involving smooth chute spillways, except in the area surrounding the base of the stepped spillway, where high pressure fluctuations may occur. …”

Pseudopolymorphism of a Highly Adaptable Tetraarylpyrene Host that Exhibits Abundant Solid-State Guest Inclusion Bằng Palani Natarajan (1490383)

“…Tetraarylpyrene host 1,3,6,8-tetrakis­(2,6-dimethyl-4-methoxyphenyl)­pyrene (TP) is found to crystallize with inclusion of diverse guests in two different modifications with simple variation of the crystallization conditions involving addition of a cosolvent. While the guest stoichiometry is found to vary in the pseudopolymorphs with some guests, polymorphic behavior of the host–guest compounds is observed with cyclohexenone and toluene as guests. …”

A Cationic Terminal Methylene Complex of Ir(I) Supported by a Pincer Ligand Bằng Jesus Campos (1950427)

“…An ylide compound, <b>3</b>, resulted from the reaction between [(PONOP)­Ir­(CH₂)]⁺ and PMe₃, while the η²-alkene complex <b>5</b> formed in a CC coupling reaction involving the methylene ligand of <b>2</b> and ethyl diazoacetate. …”

Discrete element modeling of non-spherical particles using a spherical shape Bằng Elias Gomes Santos (10485811)

“…However, in applications involving a considerable number of particles, the analysis can become impracticable. …”