Synthesis and Reactivity of Titanium Hydrazido Complexes Supported by Diamido-Ether Ligands od Junjuda Unruangsri (1955257)

“…With Ar′NCS the [2+2] cycloaddition product Ti­(N₂O)­{N­(NPh₂)­C­(NAr′)­S}­(py) was obtained, and with Ar′NCSe a mixture was formed including Ti₂(N₂O)₂(μ-Se)₂. …”

Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η³(<i>BCC</i>)-Triarylborane Coordination od David J. H. Emslie (1425715)

“…By contrast, the TXPB ligand in <b>2</b> is bound to palladium not only via the phosphine and thioether donors but also through a Pd-(η³-BAr₃) linkage involving boron and the <i>ipso</i>- and <i>ortho</i>-carbon atoms of one <i>B</i>-phenyl ring. …”

C−C and C−N Coupling Reactions of an Imidotitanium Complex with Isocyanides od Allan Bashall (3077106)

“…These products are thought to be formed in a reaction sequence involving intermediates that are analogous to the stable complexes <b>2</b> and <b>3a</b>−<b>h</b>. …”

Assembly of Soft Metal Complexes of an O₄S₂‑Macrocycle Displaying Endocyclic Monomer, Dumbbell-Like Dimer, and Endo-/Exocyclic Polymer Structures od Huiyeong Ju (1493002)

“…The X-ray structures of seven complexes (<b>1</b>–<b>7</b>) have been determined, and a range of structural types and coordination modes, including discrete to continuous forms, mono- to multinuclear, and endo- to exocyclic structures involving M–S bonds, are presented. …”

Influence of the Ligand Alkyl Chain Length on the Solubility, Aqueous Speciation, and Kinetics of Substitution Reactions of Water-Soluble M₃S₄ (M = Mo, W) Clu... od Tomás F. Beltrán (1687288)

“…On the basis of the kinetic results, a mechanism with two parallel reaction pathways involving water and OH^– attacks is proposed for the formal substitution of halides by hydroxo ligands. …”

Distinct GluN1 and GluN2 Structural Determinants for Subunit-Selective Positive Allosteric Modulation of <i>N</i>‑Methyl‑d‑aspartate Receptors od Katie L. Strong (4172584)

“…Several neurological disorders may involve NMDAR hypofunction, which has driven therapeutic interest in positive allosteric modulators (PAMs) of NMDAR function. …”

Mononuclear Titanium(IV)−Citrate Complexes from Aqueous Solutions:  pH-Specific Synthesis and Structural and Spectroscopic Studies in Relevance to Aqueous Titanium(IV)−Citrate Spec... od E. T. Kefalas (2679103)

“…In an effort to comprehend the involvement of titanium in requisite biological interactions with physiological ligands, synthetic efforts were launched targeting aqueous soluble species of Ti(IV). …”

Trinuclear Nickel Complexes with Triplesalen Ligands:  Simultaneous Occurrence of Mixed Valence and Valence Tautomerism in the Oxidized Species od Thorsten Glaser (1354377)

“…Thus, these oxidized forms exhibit the phenomena of valence tautomerism and mixed valence simultaneously. …”

Alkylation, Cation Formation, and Insertion Reactions in Titanium Tris(ketimide) Complexes od M. João Ferreira (2512048)

“…Above 60 °C, C₆F₅ is transferred to the metal center and Ti(NC^tBu₂)₃(C₆F₅) (<b>9</b>) forms. This compound participates in a dynamic process in solution involving Ti···F interactions. …”

Trinuclear Nickel Complexes with Triplesalen Ligands:  Simultaneous Occurrence of Mixed Valence and Valence Tautomerism in the Oxidized Species od Thorsten Glaser (1354377)

“…Thus, these oxidized forms exhibit the phenomena of valence tautomerism and mixed valence simultaneously. …”

Study selection flow chart. od Stella Sarpomaa Oppong (22530606)

“…</p><p>Methods</p><p>Studies will be considered eligible if they are randomized controlled trials (RCTs), quasi-experimental studies, and Observational studies (cohort, case-control, cross-sectional studies) involving women and couples with infertility problems and living in a LMIC who received a psychosocial intervention to improve marital intimacy, sexual satisfaction, and QoL. …”

Network assessment of demethylation treatment in melanoma: Differential transcriptome-methylome and antigen profile signatures od Zhijie Jiang (355840)

“…Overall, the non-metastatic SKMEL-2 map reveals post-treatment re-activation of a richer pathway landscape, involving cadherins and integrins as signatures of cell adhesion and proliferation. …”

Data supporting the figures and supplementary figures and tables in the published article: Suppression of FOXM1 activities and breast cancer growth in vitro and in vivo by a new cl... od Yvonne Ziegler (7548729)

“…</div><div><br></div><div><b>Study approval:</b> All experiments involving animals were conducted in accordance with National Institutes of Health (NIH) standards for the care and use of animals, with protocols approved by the University of Illinois IACUC.…”

Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η³(<i>BCC</i>)-Triarylborane Coordination od David J. H. Emslie (1425715)

“…By contrast, the TXPB ligand in <b>2</b> is bound to palladium not only via the phosphine and thioether donors but also through a Pd-(η³-BAr₃) linkage involving boron and the <i>ipso</i>- and <i>ortho</i>-carbon atoms of one <i>B</i>-phenyl ring. …”

Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η³(<i>BCC</i>)-Triarylborane Coordination od David J. H. Emslie (1425715)

“…By contrast, the TXPB ligand in <b>2</b> is bound to palladium not only via the phosphine and thioether donors but also through a Pd-(η³-BAr₃) linkage involving boron and the <i>ipso</i>- and <i>ortho</i>-carbon atoms of one <i>B</i>-phenyl ring. …”

Challenges in water supply systems and service delivery in the Mankweng Cluster : perspectives from households, ward councillors, and the Polokwane Municipality od Meisie Rasakanya (21655700)

“…Through a mixed-methods approach involving questionnaires distributed to 200 households across seven wards and interviews with municipal officials and ward councillors, the study found that most residents are forced to rely on unsafe water sources like rivers and ponds, thereby endangering public health. …”

Induction of autophagy through CLEC4E in combination with TLR4: an innovative strategy to restrict the survival of <i>Mycobacterium tuberculosis</i> od Susanta Pahari (37943)

“…This study suggests a unique immunotherapeutic approach involving CLEC4E in conjunction with TLR4 to restrict the survival of <i>Mtb</i> through autophagy.…”

Zirconium Hydrazides as Metallanitrene Synthons: Release of Molecular N₂ from a Hydrazinediido Complex Induced by Oxidative N–N Bond Cleavage od Thorsten Gehrmann (1933480)

“…A crossover labeling experiment employing a 1:1 mixture of <b>1</b> and ¹⁵N_α-labeled <b>1-</b>^<b>15</b><b>N</b> revealed that the isotope distribution is, as expected, statistical 1:2:1 (¹⁴N₂: ^14/15N₂: ¹⁵N₂), which is consistent with a reaction pathway involving a dinuclear intermediate in the dinitrogen-forming step. …”

Further Studies on the Substitutional Behavior of 1,2-Mo₂Br₂(CH₂SiMe₃)₄. Alkyl, Amide, Phosphide, Alkoxide, and Thiolate for... od Malcolm H. Chisholm (1468825)

“…Reactions involving 1,2-Mo₂Br₂(CH₂SiMe₃)₄ and each of LiNMe₂ and HNMe₂ in hexane at −50 °C proceed to give 1,1‘-Mo₂(NMe₂)BrR₄, where R = CH₂SiMe₃, as the first product of Br for amide exchange at the Mo₂⁶⁺ center. …”

Data_Sheet_1_A Novel Vaccine Strategy Employing Serologically Different Chimpanzee Adenoviral Vectors for the Prevention of HIV-1 and HCV Coinfection.docx od Felicity Hartnell (6242837)

“…We developed a novel vaccination regimen involving replication-defective and serologically distinct chimpanzee adenovirus (ChAd3, ChAd63) vector priming followed by modified vaccinia Ankara (MVA) boosts, for simultaneous delivery of HCV non-structural (NSmut) and HIV-1 conserved (HIVconsv) region immunogens.…”