Valve Sparing in Type A Aortic Dissection Autor Vishal Shah (5651)

“…<br><br>Given the extensive involvement of the aortic root and the age of the patient, a decision was made to perform a valve sparing surgery. …”

Directed Synthesis of the Triangular Mixed-Metal Cluster H₂RhRe₂Cp*(CO)₉: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of C... Autor Shih-Huang Huang (2148001)

“…On the basis of the first-order rate constants and the Eyring activation parameters (Δ<i>H</i>^⧧ = 25.0(8) kcal/mol; Δ<i>S</i>^⧧ = −2.6(3) eu), a rate-limiting step involving a polyhedral opening of <b>4</b> is supported. …”

Dynamics of the O‑Atom Exchange Reaction ¹⁶O(³<i>P</i>) + ¹⁸O¹⁸O(³Σ_g^–) → ¹⁶O¹⁸O(<... Autor Sridhar A. Lahankar (1294842)

“…Collisions in the former regime produce ¹⁶O¹⁸O with internal energy closer to the maximum available energy while the latter mechanism, involving strong interaction within the O₃ potential well, is responsible for the low-energy peak of the product translational distribution. …”

Structural Diversity in Supramolecular Complexes of MCl₃ (M = As, Sb, Bi) with Constrained Thio- and Seleno-Ether Ligands Autor William Levason (1275612)

“…[BiCl₃{<i>o</i>-C₆H₄(SeMe)₂}] comprises distorted square pyramidal units involving pyramidal BiCl₃ primary coordination and a weakly chelating diselenoether ligand, and assembled into infinite chains through long bridging Bi···Cl interactions via all three Clʼs. …”

Single-Molecule Magnets:  Two-Electron Reduced Version of a Mn₁₂ Complex and Environmental Influences on the Magnetization Relaxation of (PPh₄)₂[Mn... Autor Monica Soler (2337547)

“…Complexes <b>4a</b> and <b>4b</b> give resolvable frequency-dependent out-of-phase (χ_M‘ ‘) signals in AC susceptibility studies resulting from the magnetization relaxation of SMMs. …”

Preparation, Structure, and Properties of the Corner-Shared Double Cubes [Mo₆HgQ₈(H₂O)₁₈]⁸⁺ (Q = S, Se) and Tungsten Analogue... Autor Vladimir P. Fedin (1491637)

“…Furthermore, on dilution of column-purified [Mo₆HgS₈(H₂O)₁₈]⁸⁺, Beer's law is not obeyed and equilibria involving 2[Mo₃S₄(H₂O)₉]⁴⁺ are apparent. …”

Supporting Information tables, figures, and text. Autor Jerome Deval (432310)

“…Three binding metrics were computed for each docking pose: 1) RMSD (Å) to the natural CDP ligand; 2) number of hydrogen bonds formed with the crystallographically resolved water molecule anticipated to catalyze the formation of the new phosphodiester bond to the incoming nucleotide; and 3) number of hydrogen bonds formed with the RNA template (B) Docked binding modes for 2'F-2'Me-, 2'F-4'ClCH₂-, and 2'F-4'N₃-CDP were overlaid with the CDP (yellow) X-ray binding mode for reference. …”

E06918: Aldhelm's poem On the Church of Mary Built by Bugga records the consecration on 15/16 August of a church with an apse dedicated to *Mary (Mother of Christ, S00033), constru... Autor bsavill (10125827)

“…The new church has many ornaments: a golden cloth glistens with its twisted threads and forms a beautiful covering for the sacred altar. …”

Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenid... Autor Noorjahan Begum (2388037)

“…Compounds <b>3</b>, <b>6</b>, <b>7</b>, and <b>10</b> exhibit restricted fluxional behavior involving the μ-EPh moieties.…”

Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenid... Autor Noorjahan Begum (2388037)

“…Compounds <b>3</b>, <b>6</b>, <b>7</b>, and <b>10</b> exhibit restricted fluxional behavior involving the μ-EPh moieties.…”

Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenid... Autor Noorjahan Begum (2388037)

“…Compounds <b>3</b>, <b>6</b>, <b>7</b>, and <b>10</b> exhibit restricted fluxional behavior involving the μ-EPh moieties.…”

Reactions of Diamidonaphthalene-Bridged Diiridium Tetrahydrides with Alkynes:  Hydrogenation, Vinylidene Formation, and Catalytic C−C Coupling Autor M. Victoria Jiménez (2457487)

“…A similar reaction with bis(trimethylsilyl)acetylene forms the bis-vinylidene complex [Ir₂{μ-1,8-(NH)₂C₁₀H₆){CC(SiMe₃)₂}₂(P<i>i</i>Pr₃)₂] (<b>11</b>) together with 2 equiv of H₂CC(SiMe₃)₂. …”

Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenid... Autor Noorjahan Begum (2388037)

“…Compounds <b>3</b>, <b>6</b>, <b>7</b>, and <b>10</b> exhibit restricted fluxional behavior involving the μ-EPh moieties.…”

Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenid... Autor Noorjahan Begum (2388037)

“…Compounds <b>3</b>, <b>6</b>, <b>7</b>, and <b>10</b> exhibit restricted fluxional behavior involving the μ-EPh moieties.…”

Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenid... Autor Noorjahan Begum (2388037)

“…Compounds <b>3</b>, <b>6</b>, <b>7</b>, and <b>10</b> exhibit restricted fluxional behavior involving the μ-EPh moieties.…”

Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers That Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H₂meppp = <i>meso</i>-1,3-Bis[... Autor Bunsho Kure (1536136)

“…The reaction is assumed to involve an alkenyl complex, [Ni­(μ-meppp)­RhCp*­(CHCHPh)]­NO₃ (<b>9a</b>), formed through an insertion of phenylacetylene into the metal–hydride bond. …”

Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers That Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H₂meppp = <i>meso</i>-1,3-Bis[... Autor Bunsho Kure (1536136)

“…The reaction is assumed to involve an alkenyl complex, [Ni­(μ-meppp)­RhCp*­(CHCHPh)]­NO₃ (<b>9a</b>), formed through an insertion of phenylacetylene into the metal–hydride bond. …”

[Mn₁₂O₁₂(OMe)₂(O₂CPh)₁₆(H₂O)₂]^2- Single-Molecule Magnets and Other Manganese Compounds from... Autor Anastasios J. Tasiopoulos (1397299)

“…A new synthetic procedure has been developed in Mn cluster chemistry involving reductive aggregation of permanganate (MnO₄^-) ions in MeOH in the presence of benzoic acid, and the first products from its use are described. …”

System enablers and barriers to continuity of care for First Nations people living with chronic conditions: A rapid qualitative review protocol Autor Maria Alejandra Pinero de Plaza (9535079)

“…Any disagreements will be resolved through discussion or with one or more additional reviewers. …”

New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis Autor Masanari Hirahara (1558075)

“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b>_<b>2</b><b>(OH)­(OH</b>_<b>2</b><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru^III–OH:Ru^III–OH state species as a resting state. …”