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Mostrando 28,561 - 28,566 Resultados de 28,566 Para Buscar 'form is (((((revolves. OR removedddddds.) OR revolves.) OR evolved.) OR involved.) OR involves.)', tiempo de consulta: 0.68s Limitar resultados
  1. 28561
    Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>N</i>,<i>N</i>′,<i>N</i>″‑Tris(3,5-xylyl)guanidinatoplatinum(II) Bis(phosphine) Complexes. Syntheses, Structural and Theoretical Studies

    Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>... por Rishabh Ujjval (9454247)

    Publicado 2020
    “…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt­{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}­{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF<sub>3</sub>] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt­{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}­{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF<sub>3</sub>] (<b>16</b>′), is a kinetically controlled product.…”
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  2. 28562
    Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025)

    Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025) por Thomas Gernon (11046150)

    Publicado 2025
    “…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”
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  3. 28563
    Reactivity of the Phosphinidene-Bridged Complexes [Mo<sub>2</sub>Cp(μ-κ<sup>1</sup>:κ<sup>1</sup>,η<sup>5</sup>-PC<sub>5</sub>H<sub>4</sub>)(η<sup>6</sup>-1,3,5-C<sub>6</sub>H<sub>3</sub><sup><i>t</i></sup>Bu<sub>3</sub>)(CO)<sub>2</sub>] and [Mo<sub>2</sub>Cp<sub>2</sub>(μ-PH)(η<sup>6</sup>-1,3,5-C<sub>6</sub>H<sub>3</sub><sup><i>t</i></sup>Bu<sub>3</sub>)(CO)<sub>2</sub>] toward Alkynes: Multicomponent Reactions in the Presence of Ligands

    Reactivity of the Phosphinidene-Bridged Complexes [Mo<sub>2</sub>Cp(μ-κ<sup>1</sup>:κ<sup>1</sup>,η<sup>5</sup>-PC<sub>5</sub>H<sub>4</sub>)(η<sup>6</sup>-1,3,5-C<sub>6</sub>H<sub>... por M. Angeles Alvarez (1353513)

    Publicado 2012
    “…A side product was also formed during the photochemical treatment of the dicarbonyl substrate, it being finally isolated after chromatographic workup as the alkenylphosphide-chloride complex [Mo<sub>2</sub>CpCl­{μ-κ<sup>1</sup>,η<sup>5</sup>:κ<sup>1</sup>,η<sup>2</sup>-(C<sub>5</sub>H<sub>4</sub>)­PC­(CO<sub>2</sub>Me)CH­(CO<sub>2</sub>Me)}­(η<sup>6</sup>-HMes*)­(CO)] (Mo–P = 2.553(2) and 2.436(2) Ǻ).…”
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  4. 28564
    Structurally Flexible and Solution Stable [Ln<sub>4</sub>TM<sub>8</sub>(OH)<sub>8</sub>(L)<sub>8</sub>(O<sub>2</sub>CR)<sub>8</sub>(MeOH)<sub><i>y</i></sub>](ClO<sub>4</sub>)<sub>4</sub>: A Playground for Magnetic Refrigeration

    Structurally Flexible and Solution Stable [Ln<sub>4</sub>TM<sub>8</sub>(OH)<sub>8</sub>(L)<sub>8</sub>(O<sub>2</sub>CR)<sub>8</sub>(MeOH)<sub><i>y</i></sub>](ClO<sub>4</sub>)<sub>4... por Thomas N. Hooper (1670185)

    Publicado 2016
    “…This family of compounds offers an excellent playground for probing how the magnetocaloric effect evolves by introducing either antiferromagnetic or ferromagnetic interactions, or magnetic anisotropy, by substituting the nonmagnetic Zn<sup>II</sup> (<b>1a</b>) with Cu<sup>II</sup> (<b>2a</b>), Ni<sup>II</sup> (<b>6a</b>) or Co<sup>II</sup> (<b>7a</b>), respectively. …”
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  5. 28565
    Structural and Kinetic Study of Reversible CO<sub>2</sub> Fixation by Dicopper Macrocyclic Complexes. From Intramolecular Binding to Self-Assembly of Molecular Boxes

    Structural and Kinetic Study of Reversible CO<sub>2</sub> Fixation by Dicopper Macrocyclic Complexes. From Intramolecular Binding to Self-Assembly of Molecular Boxes por Anna Company (1312992)

    Publicado 2007
    “…Under a N<sub>2</sub> atmosphere the complexes evolve CO<sub>2</sub> and revert to the starting hydroxo complexes <b>1</b>(CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub> and <b>2</b>(CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub>, a reaction the rate of which linearly depends on [H<sub>2</sub>O]. …”
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  6. 28566
    Reactivity of Silyl-Substituted Iron–Platinum Hydride Complexes toward Unsaturated Molecules: 4. Insertion of Fluorinated Aromatic Alkynes into the Platinum–Hydride Bond. Synthesis and Reactivity of Heterobimetallic Dimetallacylopentenone, Dimetallacyclobutene, μ‑Vinylidene, and μ<sub>2</sub>‑σ-Alkenyl Complexes

    Reactivity of Silyl-Substituted Iron–Platinum Hydride Complexes toward Unsaturated Molecules: 4. Insertion of Fluorinated Aromatic Alkynes into the Platinum–Hydride Bond. Synthesis... por Isabelle Jourdain (102820)

    Publicado 2016
    “…In contrast, treatment of <b>1a</b> with <i>o</i>-FC<sub>6</sub>H<sub>4</sub>CCH produces first [(OC)<sub>3</sub>Fe­{μ-Si­(OMe)<sub>2</sub>(OMe)}­(μ-dppm)­Pt­(<i>o</i>-FC<sub>6</sub>H<sub>4</sub>CCH<sub>2</sub>)] (<b>2b</b>), which evolves to the dimetallacyclopentenone complex [(OC)<sub>2</sub>Fe­(μ-dppm)­{μ-C­(O)­C­(H)C­(C<sub>6</sub>H<sub>4</sub>F-<i>o</i>)}­Pt­(PPh<sub>3</sub>)] (<b>4b′</b>). …”
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