検索結果 25,041 - 25,043 結果 / 25,043 検索語 'form is (((((revolves. OR removedddddds.) OR revolves.) OR evolvesd.) OR involved.) OR involves.)*', 処理時間: 1.00秒 結果の絞り込み
  1. 25041

    Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>... 著者: Rishabh Ujjval (9454247)

    出版事項 2020
    “…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt­{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}­{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF<sub>3</sub>] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt­{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}­{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF<sub>3</sub>] (<b>16</b>′), is a kinetically controlled product.…”
  2. 25042

    Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025) 著者: Thomas Gernon (11046150)

    出版事項 2025
    “…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”
  3. 25043

    17- and 19-Electron Complexes [Fe<sup>III</sup>(η<sup>5</sup>-C<sub>5</sub>R<sub>5</sub>)(S<sub>2</sub>CNMe<sub>2</sub>)L]<sup><i>n</i>+</sup> (<i>n</i> = 1, 0):  Electronic Struct... 著者: Marie-Hélène Delville-Desbois (2995521)

    出版事項 1996
    “…The cyclic voltammogram of <b>9<sup>+</sup>PF<sub>6</sub><sup>-</sup></b> under continuous scanning for the monoelectronic reduction and the two monoelectronic reductions showed the decrease of the waves of <b>9<sup>+</sup>PF<sub>6</sub><sup>-</sup></b> and the concomitant increase of those due to the partially decoordinated dtc complexes formed upon reduction. This permits an interpretation of the CV in terms of a triple-square scheme involving <b>9</b><sup>+/<b>0</b>/-</sup>, <b>9‘</b><sup>+/<b>0</b>/-</sup>, and solvent (DMF) adducts in 18- and 19e states.…”