New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis od Masanari Hirahara (1558075)

“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b>_<b>2</b><b>(OH)­(OH</b>_<b>2</b><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru^III–OH:Ru^III–OH state species as a resting state. …”

New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis od Masanari Hirahara (1558075)

“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b>_<b>2</b><b>(OH)­(OH</b>_<b>2</b><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru^III–OH:Ru^III–OH state species as a resting state. …”

New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis od Masanari Hirahara (1558075)

“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b>_<b>2</b><b>(OH)­(OH</b>_<b>2</b><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru^III–OH:Ru^III–OH state species as a resting state. …”

Mixed-Metal Cluster Chemistry. 30. Syntheses and Optical Limiting Properties of Cluster-Containing Oligo- and Polyurethanes od Michael D. Randles (2034709)

“…Some insight into the mechanism by which these clusters function as optical limiters has been gleaned from complementary pump−probe studies, with their behavior consistent with a fast nonlinear absorption process followed by reverse saturable absorption involving metastable excited states of greater than nanosecond lifetime.…”

Eh!woza Learner Doccies od Anastasia Koch (9420299)

“…</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. …”

Single-Molecule Magnets:  Two-Electron Reduced Version of a Mn₁₂ Complex and Environmental Influences on the Magnetization Relaxation of (PPh₄)₂[Mn... od Monica Soler (2337547)

“…Complexes <b>4a</b> and <b>4b</b> give resolvable frequency-dependent out-of-phase (χ_M‘ ‘) signals in AC susceptibility studies resulting from the magnetization relaxation of SMMs. …”

W₂Cl₄(NR₂)₂(PR‘₃)₂ Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and... od F. Albert Cotton (1781341)

“…The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. …”

Unusual [Pt{κ²(<i>C</i>,<i>N</i>)}]⁺ → [Pt{κ²(<i>N</i>,<i>N</i>)}]⁺ Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>... od Rishabh Ujjval (9454247)

“…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt­{κ²(<i>C</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt­{κ²(<i>N</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>16</b>′), is a kinetically controlled product.…”

Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025) od Thomas Gernon (11046150)

“…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”

17- and 19-Electron Complexes [Fe^III(η⁵-C₅R₅)(S₂CNMe₂)L]^<i>n</i>+ (<i>n</i> = 1, 0):  Electronic Struct... od Marie-Hélène Delville-Desbois (2995521)

“…The cyclic voltammogram of <b>9⁺PF₆^-</b> under continuous scanning for the monoelectronic reduction and the two monoelectronic reductions showed the decrease of the waves of <b>9⁺PF₆^-</b> and the concomitant increase of those due to the partially decoordinated dtc complexes formed upon reduction. This permits an interpretation of the CV in terms of a triple-square scheme involving <b>9</b>^+/<b>0</b>/-, <b>9‘</b>^+/<b>0</b>/-, and solvent (DMF) adducts in 18- and 19e states.…”

E00144: Coptic Stories of the Monks of the Desert, attributed in the text to Paphnouthios, possibly Paphnouthios of Scetis, 4th c., which describe the lives and miracles of two bis... od Bryan (10112260)

“…<br> <br>The second part (fol. 11b–37a) forms a history of the Bishops of Philae, from the see’s foundation to the death of bishop *Pseleusias (who is different from the monk Pseleusius). …”

E06111: The ‘epic’ Greek Martyrdom of *Christophoros (martyr of Pamphylia, S00616) tells of Reprebos, an outwardly repulsive barbarian from a tribe of cannibals, who is baptised a... od Nikolaos (10112551)

“…Christophoros is nailed to a bronze bench, while around him wood is piled forming a circular covered structure, which is then doused with oil and set on fire.…”