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28561
W<sub>2</sub>Cl<sub>4</sub>(NR<sub>2</sub>)<sub>2</sub>(PR‘<sub>3</sub>)<sub>2</sub> Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and...
Publicat 1997“…The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. …”
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28562
Unusual [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}]<sup>+</sup> → [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}]<sup>+</sup> Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>...
Publicat 2020“…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt{κ<sup>2</sup>(<i>C</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt{κ<sup>2</sup>(<i>N</i>,<i>N</i>)}{κ<sup>2</sup>(<i>P</i>,<i>P</i>)}][OC(O)CF<sub>3</sub>] (<b>16</b>′), is a kinetically controlled product.…”
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28563
Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025)
Publicat 2025“…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”
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28564
Reactivity of the Phosphinidene-Bridged Complexes [Mo<sub>2</sub>Cp(μ-κ<sup>1</sup>:κ<sup>1</sup>,η<sup>5</sup>-PC<sub>5</sub>H<sub>4</sub>)(η<sup>6</sup>-1,3,5-C<sub>6</sub>H<sub>...
Publicat 2012“…A side product was also formed during the photochemical treatment of the dicarbonyl substrate, it being finally isolated after chromatographic workup as the alkenylphosphide-chloride complex [Mo<sub>2</sub>CpCl{μ-κ<sup>1</sup>,η<sup>5</sup>:κ<sup>1</sup>,η<sup>2</sup>-(C<sub>5</sub>H<sub>4</sub>)PC(CO<sub>2</sub>Me)CH(CO<sub>2</sub>Me)}(η<sup>6</sup>-HMes*)(CO)] (Mo–P = 2.553(2) and 2.436(2) Ǻ).…”
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28565
Structural and Kinetic Study of Reversible CO<sub>2</sub> Fixation by Dicopper Macrocyclic Complexes. From Intramolecular Binding to Self-Assembly of Molecular Boxes
Publicat 2007“…Under a N<sub>2</sub> atmosphere the complexes evolve CO<sub>2</sub> and revert to the starting hydroxo complexes <b>1</b>(CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub> and <b>2</b>(CF<sub>3</sub>SO<sub>3</sub>)<sub>2</sub>, a reaction the rate of which linearly depends on [H<sub>2</sub>O]. …”
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28566
Degradation of triazine-2-14C metsulfuron–methyl in soil from an oil palm plantation
Publicat 2015“…Results of microbial colonies counted were expressed in colony forming units (CFU).</p> <p>Table 1. Soil characterization.…”