Hydrogen-Bonded Networks of Ammonium Bis- and Tetrakisphosphonates—Synthesis, High-Throughput Screening and Structural Trends за авторством Monika Plabst (2329927)

“...Four different motifs of hydrogen bonding between the phosphonate groups could be observed: a single hydrogen bond, a dimeric <i>R</i>₂²(8) ring motif, the association of two bisphosphonate units into a dimer by two 2-fold hydrogen bonds, and an intramolecular hydrogen bond forming a six-membered ring. Cross-linking of the bisphosphonate groups via [O−H···O] bridges between phosphonates and in some cases solvent molecules generates two-dimensional networks. ...”

Image 1_Investigating the regulation of the miR-199a-3p/TGF-β/Smad signaling pathway by BSHXF drug-containing serum combined with ADSCs for delaying intervertebral disc degeneratio... за авторством Enxu Liu (21190403)

“...BSHXF, a classical traditional Chinese medicine formula, demonstrates dual pharmacological actions: tonifying kidneys, strengthening bones, activating blood circulation, and resolving stasis. It has been widely used in IDD management. ...”

PKD1 association with nNOS is enhanced by kinase activation in a PDZ-ligand independent manner. за авторством Lucía Sánchez-Ruiloba (552971)

“...Analysis of nNOS immunoprecipitates showed that PKD1/nNOS complexes are still formed after deletion of PKD1 PDZ-ligand. Representative images from three independent experiments are shown in panels A, B, C and D. ...”

Hydrogen-Bonded Networks of Ammonium Bis- and Tetrakisphosphonates—Synthesis, High-Throughput Screening and Structural Trends за авторством Monika Plabst (2329927)

“...Four different motifs of hydrogen bonding between the phosphonate groups could be observed: a single hydrogen bond, a dimeric <i>R</i>₂²(8) ring motif, the association of two bisphosphonate units into a dimer by two 2-fold hydrogen bonds, and an intramolecular hydrogen bond forming a six-membered ring. Cross-linking of the bisphosphonate groups via [O−H···O] bridges between phosphonates and in some cases solvent molecules generates two-dimensional networks. ...”

The recombinant CgPst2^<i>R174A</i> and CgPst2-CΔ^{<i>R174-F198</i>} proteins do not exhibit NADH:quinone oxidoreductase activity. за авторством Anamika Battu (10197220)

“...</b> proteins, along with the flow through, were resolved on 12% SDS-PAGE, and stained with Coomassie Brilliant Blue. ...”

Hydrogen-Bonded Networks of Ammonium Bis- and Tetrakisphosphonates—Synthesis, High-Throughput Screening and Structural Trends за авторством Monika Plabst (2329927)

“...Four different motifs of hydrogen bonding between the phosphonate groups could be observed: a single hydrogen bond, a dimeric <i>R</i>₂²(8) ring motif, the association of two bisphosphonate units into a dimer by two 2-fold hydrogen bonds, and an intramolecular hydrogen bond forming a six-membered ring. Cross-linking of the bisphosphonate groups via [O−H···O] bridges between phosphonates and in some cases solvent molecules generates two-dimensional networks. ...”

Magnetic Coupling through the Carbon Skeleton of Malonate in Two Polymorphs of {[Cu(bpy)(H₂O)][Cu(bpy)(mal)(H₂O)]}(ClO₄)₂ (H₂... за авторством Catalina Ruiz-Pérez (2421457)

“...Compounds <b>1</b> and <b>2</b> contain four crystallographically independent copper(II) atoms, but the environment of all of them is distorted square pyramidal:  the axial position is occupied by a water molecule, whereas the equatorial plane is formed by a chelating bpy and either a bidentate malonate or two carboxylate oxygens from two malonate groups. ...”

Control of Charge Transfer in a Series of Ru₂^II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magneti... за авторством Hitoshi Miyasaka (1507285)

“...This result is consistent with the fact that TCNQF₄ has the strongest electron affinity among the TCNQR_<i>x</i> molecules. Even in neutral forms, however, <b>1</b>−<b>4</b> can be observed to undergo thermally and/or field-activated charge transfers from [Ru₂^II,II] to TCNQR_<i>x</i> to give semiconductors with an activation energy of 200−300 meV, which is a driving force to transport electrons over the lattice. ...”

Control of Charge Transfer in a Series of Ru₂^II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magneti... за авторством Hitoshi Miyasaka (1507285)

“...This result is consistent with the fact that TCNQF₄ has the strongest electron affinity among the TCNQR_<i>x</i> molecules. Even in neutral forms, however, <b>1</b>−<b>4</b> can be observed to undergo thermally and/or field-activated charge transfers from [Ru₂^II,II] to TCNQR_<i>x</i> to give semiconductors with an activation energy of 200−300 meV, which is a driving force to transport electrons over the lattice. ...”

Syntheses, Structures, Magnetic Properties, and X-ray Absorption Spectra of Carnotite-type Uranyl Chromium(V) Oxides:  A[(UO₂)₂Cr₂O₈](H<... за авторством A. J. Locock (2720668)

“...Four uranyl chromium(V) oxides were synthesized by mild hydrothermal methods and their structures were solved using single-crystal X-ray diffraction data. ...”

Control of Charge Transfer in a Series of Ru₂^II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magneti... за авторством Hitoshi Miyasaka (1507285)

“...This result is consistent with the fact that TCNQF₄ has the strongest electron affinity among the TCNQR_<i>x</i> molecules. Even in neutral forms, however, <b>1</b>−<b>4</b> can be observed to undergo thermally and/or field-activated charge transfers from [Ru₂^II,II] to TCNQR_<i>x</i> to give semiconductors with an activation energy of 200−300 meV, which is a driving force to transport electrons over the lattice. ...”

New Oxamato-Bridged Trinuclear Cu^II−Cu^II−Cu^II Complexes with Hydrogen-Bond Supramolecular Structures:  Synthesis and Magneto−Structural Studies... за авторством Javier Tercero (2343754)

“...Their crystal structures were solved. Complex <b>1</b> crystallizes in the monoclinic system, space group <i>P</i>2₁, with <i>a = </i>15.8364(3) Å, <i>b = </i>8.4592(2) Å, <i>c</i> = 15.952 Å, β = 101.9070(10)°, and <i>Z</i> = 2. ...”

Interoperable Infrastructures for Digital Research: A proposed pathway for enabling transformation за авторством Adam Farquhar (591979)

“...These assets have grown to include millions of items and petabytes of material covering all forms of content – manuscripts, monographs, maps, images, sound, and more. ...”

Control of Charge Transfer in a Series of Ru₂^II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magneti... за авторством Hitoshi Miyasaka (1507285)

“...This result is consistent with the fact that TCNQF₄ has the strongest electron affinity among the TCNQR_<i>x</i> molecules. Even in neutral forms, however, <b>1</b>−<b>4</b> can be observed to undergo thermally and/or field-activated charge transfers from [Ru₂^II,II] to TCNQR_<i>x</i> to give semiconductors with an activation energy of 200−300 meV, which is a driving force to transport electrons over the lattice. ...”

Control of Charge Transfer in a Series of Ru₂^II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magneti... за авторством Hitoshi Miyasaka (1507285)

“...This result is consistent with the fact that TCNQF₄ has the strongest electron affinity among the TCNQR_<i>x</i> molecules. Even in neutral forms, however, <b>1</b>−<b>4</b> can be observed to undergo thermally and/or field-activated charge transfers from [Ru₂^II,II] to TCNQR_<i>x</i> to give semiconductors with an activation energy of 200−300 meV, which is a driving force to transport electrons over the lattice. ...”

Control of Charge Transfer in a Series of Ru₂^II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magneti... за авторством Hitoshi Miyasaka (1507285)

“...This result is consistent with the fact that TCNQF₄ has the strongest electron affinity among the TCNQR_<i>x</i> molecules. Even in neutral forms, however, <b>1</b>−<b>4</b> can be observed to undergo thermally and/or field-activated charge transfers from [Ru₂^II,II] to TCNQR_<i>x</i> to give semiconductors with an activation energy of 200−300 meV, which is a driving force to transport electrons over the lattice. ...”

Control of Charge Transfer in a Series of Ru₂^II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magneti... за авторством Hitoshi Miyasaka (1507285)

“...This result is consistent with the fact that TCNQF₄ has the strongest electron affinity among the TCNQR_<i>x</i> molecules. Even in neutral forms, however, <b>1</b>−<b>4</b> can be observed to undergo thermally and/or field-activated charge transfers from [Ru₂^II,II] to TCNQR_<i>x</i> to give semiconductors with an activation energy of 200−300 meV, which is a driving force to transport electrons over the lattice. ...”

Synthesis, Characterization, and Chiral Behavior of S-Bridged Co^IIIPt^IICo^III Trinuclear Complexes Composed of Bis(thiolato)-Type Octahedral Units <... за авторством Hirokazu Honda (2964768)

“...Complex [<b>1</b>]⁴⁺ formed both racemic (ΔΔ/ΛΛ) and meso (ΔΛ) forms, which were separated and optically resolved by cation-exchange column chromatography. ...”

Supporting Information tables, figures, and text. за авторством Jerome Deval (432310)

“...Three binding metrics were computed for each docking pose: 1) RMSD (Å) to the natural CDP ligand; 2) number of hydrogen bonds formed with the crystallographically resolved water molecule anticipated to catalyze the formation of the new phosphodiester bond to the incoming nucleotide; and 3) number of hydrogen bonds formed with the RNA template (B) Docked binding modes for 2'F-2'Me-, 2'F-4'ClCH₂-, and 2'F-4'N₃-CDP were overlaid with the CDP (yellow) X-ray binding mode for reference. ...”

Single-Molecule Magnets:  Two-Electron Reduced Version of a Mn₁₂ Complex and Environmental Influences on the Magnetization Relaxation of (PPh₄)₂[Mn... за авторством Monica Soler (2337547)

“...Complexes <b>4a</b> and <b>4b</b> give resolvable frequency-dependent out-of-phase (χ_M‘ ‘) signals in AC susceptibility studies resulting from the magnetization relaxation of SMMs. ...”