A Novel Family of Structurally Characterized Lithium Cobalt Double Aryloxides and the Nanoparticles and Thin Films Generated Therefrom Bằng Timothy J. Boyle (1455829)

“…Thin films of the spinel phase of LiCoO₂ were formed by spin-cast deposition methods using <b>5 </b>or <b>6</b> dissolved in a py/toluene mixture onto platinized silicon wafers followed by firing at 700 °C. …”

A Novel Family of Structurally Characterized Lithium Cobalt Double Aryloxides and the Nanoparticles and Thin Films Generated Therefrom Bằng Timothy J. Boyle (1455829)

“…Thin films of the spinel phase of LiCoO₂ were formed by spin-cast deposition methods using <b>5 </b>or <b>6</b> dissolved in a py/toluene mixture onto platinized silicon wafers followed by firing at 700 °C. …”

A Novel Family of Structurally Characterized Lithium Cobalt Double Aryloxides and the Nanoparticles and Thin Films Generated Therefrom Bằng Timothy J. Boyle (1455829)

“…Thin films of the spinel phase of LiCoO₂ were formed by spin-cast deposition methods using <b>5 </b>or <b>6</b> dissolved in a py/toluene mixture onto platinized silicon wafers followed by firing at 700 °C. …”

A Novel Family of Structurally Characterized Lithium Cobalt Double Aryloxides and the Nanoparticles and Thin Films Generated Therefrom Bằng Timothy J. Boyle (1455829)

“…Thin films of the spinel phase of LiCoO₂ were formed by spin-cast deposition methods using <b>5 </b>or <b>6</b> dissolved in a py/toluene mixture onto platinized silicon wafers followed by firing at 700 °C. …”

A Novel Family of Structurally Characterized Lithium Cobalt Double Aryloxides and the Nanoparticles and Thin Films Generated Therefrom Bằng Timothy J. Boyle (1455829)

“…Thin films of the spinel phase of LiCoO₂ were formed by spin-cast deposition methods using <b>5 </b>or <b>6</b> dissolved in a py/toluene mixture onto platinized silicon wafers followed by firing at 700 °C. …”

Unusual [Pt{κ²(<i>C</i>,<i>N</i>)}]⁺ → [Pt{κ²(<i>N</i>,<i>N</i>)}]⁺ Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>... Bằng Rishabh Ujjval (9454247)

“…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt­{κ²(<i>C</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt­{κ²(<i>N</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>16</b>′), is a kinetically controlled product.…”

Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025) Bằng Thomas Gernon (11046150)

“…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”

17- and 19-Electron Complexes [Fe^III(η⁵-C₅R₅)(S₂CNMe₂)L]^<i>n</i>+ (<i>n</i> = 1, 0):  Electronic Struct... Bằng Marie-Hélène Delville-Desbois (2995521)

“…The cyclic voltammogram of <b>9⁺PF₆^-</b> under continuous scanning for the monoelectronic reduction and the two monoelectronic reductions showed the decrease of the waves of <b>9⁺PF₆^-</b> and the concomitant increase of those due to the partially decoordinated dtc complexes formed upon reduction. This permits an interpretation of the CV in terms of a triple-square scheme involving <b>9</b>^+/<b>0</b>/-, <b>9‘</b>^+/<b>0</b>/-, and solvent (DMF) adducts in 18- and 19e states.…”

Visible, Near-Infrared, and Dual-Range Luminescence Spanning the 4f Series Sensitized by a Gallium(III)/Lanthanide(III) Metallacrown Structure Bằng Elvin V. Salerno (8736405)

“…Values obtained for <b>Yb-1</b>, that is, 0.78(4) % in CH₃OH and 8.4(1)% in CD₃OD, are among the highest ones reported today for Yb³⁺ complexes formed with nondeuterated and nonhalogenated ligands.…”

Interoperable infrastructures for digital research: a proposed pathway for enabling transformation Bằng James Baker (4466509)

“…These assets have grown to include millions of items and petabytes of material covering all forms of content – manuscripts, monographs, maps, images, sound, and more. …”

Triazenides as Suitable Ligands in the Synthesis of Palladium Compounds in Three Different Oxidation States: I, II, and III Bằng Susana Ibañez (1737721)

“…In the search for a possible first step in this catalytic oxidation process we have also performed DFT calculations exploring the potential Pd­(III) intermediate formed by axial Pd–Ph interactions.…”

Oxamato-Bridged Trinuclear Ni^IICu^IINi^II Complexes:  A New (Ni^IICu^IINi^II)₂ Hexanuclear Complex and Supra... Bằng Javier Tercero (2343754)

“…The crystal structures of <b>1</b>, <b>7</b>, and <b>8</b> were solved. For complex <b>1</b>, the trinuclear entities are linked by hydrogen bonds forming a one-dimensional system, and for complex <b>8</b>, the presence of van der Waals interactions gives a one-dimensional system, too. …”

Magnetic Coupling through the Carbon Skeleton of Malonate in Two Polymorphs of {[Cu(bpy)(H₂O)][Cu(bpy)(mal)(H₂O)]}(ClO₄)₂ (H₂... Bằng Catalina Ruiz-Pérez (2421457)

“…Compounds <b>1</b> and <b>2</b> contain four crystallographically independent copper(II) atoms, but the environment of all of them is distorted square pyramidal:  the axial position is occupied by a water molecule, whereas the equatorial plane is formed by a chelating bpy and either a bidentate malonate or two carboxylate oxygens from two malonate groups. …”

Control of Charge Transfer in a Series of Ru₂^II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magneti... Bằng Hitoshi Miyasaka (1507285)

“…This result is consistent with the fact that TCNQF₄ has the strongest electron affinity among the TCNQR_<i>x</i> molecules. Even in neutral forms, however, <b>1</b>−<b>4</b> can be observed to undergo thermally and/or field-activated charge transfers from [Ru₂^II,II] to TCNQR_<i>x</i> to give semiconductors with an activation energy of 200−300 meV, which is a driving force to transport electrons over the lattice. …”

Control of Charge Transfer in a Series of Ru₂^II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magneti... Bằng Hitoshi Miyasaka (1507285)

“…This result is consistent with the fact that TCNQF₄ has the strongest electron affinity among the TCNQR_<i>x</i> molecules. Even in neutral forms, however, <b>1</b>−<b>4</b> can be observed to undergo thermally and/or field-activated charge transfers from [Ru₂^II,II] to TCNQR_<i>x</i> to give semiconductors with an activation energy of 200−300 meV, which is a driving force to transport electrons over the lattice. …”

Syntheses, Structures, Magnetic Properties, and X-ray Absorption Spectra of Carnotite-type Uranyl Chromium(V) Oxides:  A[(UO₂)₂Cr₂O₈](H<... Bằng A. J. Locock (2720668)

“…Four uranyl chromium(V) oxides were synthesized by mild hydrothermal methods and their structures were solved using single-crystal X-ray diffraction data. …”

Control of Charge Transfer in a Series of Ru₂^II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magneti... Bằng Hitoshi Miyasaka (1507285)

“…This result is consistent with the fact that TCNQF₄ has the strongest electron affinity among the TCNQR_<i>x</i> molecules. Even in neutral forms, however, <b>1</b>−<b>4</b> can be observed to undergo thermally and/or field-activated charge transfers from [Ru₂^II,II] to TCNQR_<i>x</i> to give semiconductors with an activation energy of 200−300 meV, which is a driving force to transport electrons over the lattice. …”

New Oxamato-Bridged Trinuclear Cu^II−Cu^II−Cu^II Complexes with Hydrogen-Bond Supramolecular Structures:  Synthesis and Magneto−Structural Studies... Bằng Javier Tercero (2343754)

“…Their crystal structures were solved. Complex <b>1</b> crystallizes in the monoclinic system, space group <i>P</i>2₁, with <i>a = </i>15.8364(3) Å, <i>b = </i>8.4592(2) Å, <i>c</i> = 15.952 Å, β = 101.9070(10)°, and <i>Z</i> = 2. …”

Interoperable Infrastructures for Digital Research: A proposed pathway for enabling transformation Bằng Adam Farquhar (591979)

“…These assets have grown to include millions of items and petabytes of material covering all forms of content – manuscripts, monographs, maps, images, sound, and more. …”

Control of Charge Transfer in a Series of Ru₂^II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magneti... Bằng Hitoshi Miyasaka (1507285)

“…This result is consistent with the fact that TCNQF₄ has the strongest electron affinity among the TCNQR_<i>x</i> molecules. Even in neutral forms, however, <b>1</b>−<b>4</b> can be observed to undergo thermally and/or field-activated charge transfers from [Ru₂^II,II] to TCNQR_<i>x</i> to give semiconductors with an activation energy of 200−300 meV, which is a driving force to transport electrons over the lattice. …”