Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenid... Dahkki Noorjahan Begum (2388037)

“…Compounds <b>3</b>, <b>6</b>, <b>7</b>, and <b>10</b> exhibit restricted fluxional behavior involving the μ-EPh moieties.…”

Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers That Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H₂meppp = <i>meso</i>-1,3-Bis[... Dahkki Bunsho Kure (1536136)

“…The reaction is assumed to involve an alkenyl complex, [Ni­(μ-meppp)­RhCp*­(CHCHPh)]­NO₃ (<b>9a</b>), formed through an insertion of phenylacetylene into the metal–hydride bond. …”

Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers That Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H₂meppp = <i>meso</i>-1,3-Bis[... Dahkki Bunsho Kure (1536136)

“…The reaction is assumed to involve an alkenyl complex, [Ni­(μ-meppp)­RhCp*­(CHCHPh)]­NO₃ (<b>9a</b>), formed through an insertion of phenylacetylene into the metal–hydride bond. …”

Creative methods and practices to mobilising public health knowledge webinar Dahkki Joe Langley (2382391)

“…</p><p dir="ltr">In the field of public health, mobilising evidence and other forms of knowledge is essential to developing effective, equitable, and sustainable interventions. …”

Stereoselectivity in the Formation of Metallomacrocycles from [Mo(NO){HB(3,5-Me₂C₃HN₂)₃}I₂] and Ditopic Proligands:  The X-ra... Dahkki Ferida S. McQuillan (2962425)

“…These binuclear complexes are formed under kinetic control so that <i>syn</i>-[Mo(NO)(tp*){1,4-(OCH₂)₂C₆H₄}]₂, <b>2s</b>, forms more rapidly than <i>anti</i>-[Mo(NO)(tp*){1,4-(OCH₂)₂C₆H₄}]₂, <b>2a</b>, but in lower yield. …”

New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis Dahkki Masanari Hirahara (1558075)

“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b>_<b>2</b><b>(OH)­(OH</b>_<b>2</b><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru^III–OH:Ru^III–OH state species as a resting state. …”

New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis Dahkki Masanari Hirahara (1558075)

“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b>_<b>2</b><b>(OH)­(OH</b>_<b>2</b><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru^III–OH:Ru^III–OH state species as a resting state. …”

New Series of Dinuclear Ruthenium(II) Complexes Synthesized Using Photoisomerization for Efficient Water Oxidation Catalysis Dahkki Masanari Hirahara (1558075)

“…Bulk electrolysis of the <i>p</i>,<i>p</i>-<b>Ru</b>_<b>2</b><b>(OH)­(OH</b>_<b>2</b><b>)</b> solution corroborated the electrocatalytic cycle involving the Ru^III–OH:Ru^III–OH state species as a resting state. …”

Eh!woza Learner Doccies Dahkki Anastasia Koch (9420299)

“…</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. …”

W₂Cl₄(NR₂)₂(PR‘₃)₂ Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and... Dahkki F. Albert Cotton (1781341)

“…The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. …”

Unusual [Pt{κ²(<i>C</i>,<i>N</i>)}]⁺ → [Pt{κ²(<i>N</i>,<i>N</i>)}]⁺ Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>... Dahkki Rishabh Ujjval (9454247)

“…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt­{κ²(<i>C</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt­{κ²(<i>N</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>16</b>′), is a kinetically controlled product.…”

Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025) Dahkki Thomas Gernon (11046150)

“…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”

17- and 19-Electron Complexes [Fe^III(η⁵-C₅R₅)(S₂CNMe₂)L]^<i>n</i>+ (<i>n</i> = 1, 0):  Electronic Struct... Dahkki Marie-Hélène Delville-Desbois (2995521)

“…The cyclic voltammogram of <b>9⁺PF₆^-</b> under continuous scanning for the monoelectronic reduction and the two monoelectronic reductions showed the decrease of the waves of <b>9⁺PF₆^-</b> and the concomitant increase of those due to the partially decoordinated dtc complexes formed upon reduction. This permits an interpretation of the CV in terms of a triple-square scheme involving <b>9</b>^+/<b>0</b>/-, <b>9‘</b>^+/<b>0</b>/-, and solvent (DMF) adducts in 18- and 19e states.…”