Supporting Information tables, figures, and text. by Jerome Deval (432310)

“…Three binding metrics were computed for each docking pose: 1) RMSD (Å) to the natural CDP ligand; 2) number of hydrogen bonds formed with the crystallographically resolved water molecule anticipated to catalyze the formation of the new phosphodiester bond to the incoming nucleotide; and 3) number of hydrogen bonds formed with the RNA template (B) Docked binding modes for 2'F-2'Me-, 2'F-4'ClCH₂-, and 2'F-4'N₃-CDP were overlaid with the CDP (yellow) X-ray binding mode for reference. …”

Eh!woza Learner Doccies by Anastasia Koch (9420299)

“…</p><p dir="ltr">Other projects involve collaboration with the Khayelitsha <a href="https://www.msf.org/south-africa" target="_blank"><u>Mission of Médecins Sans Frontières</u></a> (MSF) to engage young adult survivors of drug-resistant TB. …”

Alkynyldiphenylphosphine d⁸ (Pt, Rh, Ir) Complexes:  Contrasting Behavior toward <i>cis</i>-[Pt(C₆F₅)₂(THF)₂] by Jesús R. Berenguer (2468818)

“…Thus, treatment of <b>1</b> with 1 equiv of <i>cis</i>-[Pt(C₆F₅)₂(THF)₂] gives the double inserted cationic product [Pt(C₆F₅)(S)μ-{C(Ph)C(PPh₂)C(PPh₂)C(Ph)(C₆F₅)}Pt(C₆F₅)(PPh₂C⋮CPh)](CF₃SO₃) (S = THF, H₂O), <b>8</b> (S = H₂O, X-ray), which evolves in solution to the mononuclear complex [(C₆F₅)(PPh₂C⋮CPh)Pt{C₁₀H₄-1-C₆F₅-4-Ph-2,3-κ<i>PP</i>‘(PPh₂)₂}](CF₃ SO₃), <b>9</b> (X-ray), containing a 1-pentafluorophenyl-2,3-bis(diphenylphosphine)-4-phenylnaphthalene ligand, formed by annulation of a phenyl group and loss of the Pt(C₆F₅) unit. …”

Migration and Insertion Processes in the Reactions of the Hydrocarbyl-Bridged Unsaturated Complexes [Mo₂(η⁵-C₅H₅)₂(μ-R)(μ-PCy... by M. Angeles Alvarez (1353513)

“…Finally, the phenyl-bridged complex gives again the analogous phenyl derivative [Mo₂Cp₂(Ph)(μ-PCy₂)(CO)(NO)₂], but small amounts of dinitrosyl derivatives having terminal benzoyl, [Mo₂Cp₂{C(O)Ph}(μ-PCy₂)(CO)(NO)₂], bridging benzoyl, [Mo₂Cp₂{μ-κ¹:η²-C(O)Ph}(μ-PCy₂)(NO)₂], and bridging phenyl ([Mo₂Cp₂{μ-κ¹:η²-Ph}(μ-PCy₂)(NO)₂], Mo−Mo = 2.9753(5) Å)) ligands are now formed. The latter complex can be selectively generated through the photochemical decarbonylation of the major phenyl complex. …”

Single-Molecule Magnets:  Two-Electron Reduced Version of a Mn₁₂ Complex and Environmental Influences on the Magnetization Relaxation of (PPh₄)₂[Mn... by Monica Soler (2337547)

“…Complexes <b>4a</b> and <b>4b</b> give resolvable frequency-dependent out-of-phase (χ_M‘ ‘) signals in AC susceptibility studies resulting from the magnetization relaxation of SMMs. …”

W₂Cl₄(NR₂)₂(PR‘₃)₂ Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and... by F. Albert Cotton (1781341)

“…The structure of <b>1</b> reveals that the molecule itself deviates from an eclipsed conformation with retention of a strong intramolecular N−H···Cl hydrogen bonding and the torsion angle involving the hydrogen bonded N and Cl atoms is 27.0°. …”

Major Henryk Cygielski, Virtuti Militari, Monte Cassino by Their Finest Hour Project Team (18604667)

“…Henryk was held in various camps near Moscow before being moved to Kozielsko, a site from which groups of Polish officers were removed and executed in the Katyn Massacre. By sheer luck he was sent instead to Juchnowo, where after a series of interrogations by the NKVD, forerunner of the KGB, he was sentenced to five years hard labour for ‘wearing the uniform of the Polish Army.’…”

Unusual [Pt{κ²(<i>C</i>,<i>N</i>)}]⁺ → [Pt{κ²(<i>N</i>,<i>N</i>)}]⁺ Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic <i>... by Rishabh Ujjval (9454247)

“…The mechanism associated with the coordination flip of the guanidinate(1−) ligand was mapped with the aid of DFT calculations on a model complex, [Pt­{κ²(<i>C</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>22</b>′), which revealed a pathway involving a Wheland intermediate, <b>F</b>, and further point out that the product, [Pt­{κ²(<i>N</i>,<i>N</i>)}­{κ²(<i>P</i>,<i>P</i>)}]­[OC­(O)­CF₃] (<b>16</b>′), is a kinetically controlled product.…”

Data associated with the paper "Enriched mantle generated through persistent convective erosion of continental roots" (Gernon et al., Nature Geoscience, 2025) by Thomas Gernon (11046150)

“…Borisova, and G. Xu. Involvement of continental crust in the formation of the Cretaceous Kerguelen Plateau: New perspectives from ODP Leg 120 Sites. …”

System enablers and barriers to continuity of care for First Nations people living with chronic conditions: A rapid qualitative review protocol by Maria Alejandra Pinero de Plaza (9535079)

“…Any disagreements will be resolved through discussion or with one or more additional reviewers. …”

Shape Model of Hydra by Simon Porter (9221390)

“…Shape created from the resolved images of Hydra obtained by New Horizons. …”

E00144: Coptic Stories of the Monks of the Desert, attributed in the text to Paphnouthios, possibly Paphnouthios of Scetis, 4th c., which describe the lives and miracles of two bis... by Bryan (10112260)

“…<br> <br>The second part (fol. 11b–37a) forms a history of the Bishops of Philae, from the see’s foundation to the death of bishop *Pseleusias (who is different from the monk Pseleusius). …”

Reactivity of the Phosphinidene-Bridged Complexes [Mo₂Cp(μ-κ¹:κ¹,η⁵-PC₅H₄)(η⁶-1,3,5-C₆H<sub>... by M. Angeles Alvarez (1353513)

“…A side product was also formed during the photochemical treatment of the dicarbonyl substrate, it being finally isolated after chromatographic workup as the alkenylphosphide-chloride complex [Mo₂CpCl­{μ-κ¹,η⁵:κ¹,η²-(C₅H₄)­PC­(CO₂Me)CH­(CO₂Me)}­(η⁶-HMes*)­(CO)] (Mo–P = 2.553(2) and 2.436(2) Ǻ).…”

Structurally Flexible and Solution Stable [Ln₄TM₈(OH)₈(L)₈(O₂CR)₈(MeOH)_<i>y</i>](ClO₄)<sub>4... by Thomas N. Hooper (1670185)

“…This family of compounds offers an excellent playground for probing how the magnetocaloric effect evolves by introducing either antiferromagnetic or ferromagnetic interactions, or magnetic anisotropy, by substituting the nonmagnetic Zn^II (<b>1a</b>) with Cu^II (<b>2a</b>), Ni^II (<b>6a</b>) or Co^II (<b>7a</b>), respectively. …”

Reactivity of Silyl-Substituted Iron–Platinum Hydride Complexes toward Unsaturated Molecules: 4. Insertion of Fluorinated Aromatic Alkynes into the Platinum–Hydride Bond. Synthesis... by Isabelle Jourdain (102820)

“…In contrast, treatment of <b>1a</b> with <i>o</i>-FC₆H₄CCH produces first [(OC)₃Fe­{μ-Si­(OMe)₂(OMe)}­(μ-dppm)­Pt­(<i>o</i>-FC₆H₄CCH₂)] (<b>2b</b>), which evolves to the dimetallacyclopentenone complex [(OC)₂Fe­(μ-dppm)­{μ-C­(O)­C­(H)C­(C₆H₄F-<i>o</i>)}­Pt­(PPh₃)] (<b>4b′</b>). …”

File S1 - Diminished Vision in Healthy Aging Is Associated with Increased Retinal L-Type Voltage Gated Calcium Channel Ion Influx by David Bissig (189073)

“…B: Side view, with one screen removed. The perch was constructed of a single piece of thick metal wire, padded at the hind- and forelimb placements, and secured at the center and one corner of the device floor. …”