Epoxidation of Alkenes with H2O2 Catalyzed by Dititanium-Containing 19-Tungstodiarsenate(III): Experimental and Theoretical Studies
Epoxidation of a range of alkenes with aqueous H2O2 easily proceeds in the presence of the dititanium-containing 19-tungstodiarsenate(III) [Ti2(OH)2As2W19O67(H2O)]8– (1), which contains five-coordinate Ti atoms. The results of product and kinetics studies support a mechanism that involves a reversib...
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2010
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| Online Access: | http://hdl.handle.net/10725/17247 https://doi.org/10.1002/ejic.201000615 http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejic.201000615 |
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