Investigating the role of diamagnetic Cd2+ ions on the structural, optical, and magnetic properties of YIG

In this study, Y3-xCdxFe5O12 (0.0 ≤ × ≤0.2) powders were synthesized via the co-precipitation method at calcination temperature 1100 °C. The phase formation of YIG was confirmed from X-ray powder diffraction (XRD) and Fourier Transform Infrared (FTIR) technique. The change of the band-gap energy, de...

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Bibliographic Details
Main Author: Assi, B. (author)
Other Authors: Bitar, Z. (author), Malaeb, W. (author), Hassan, R. Sayed (author), Yaacoub, N. (author), Awad, R. (author)
Format: article
Published: 2021
Online Access:http://hdl.handle.net/10725/16736
https://doi.org/10.1088/1402-4896/abfde1
http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php
https://iopscience.iop.org/article/10.1088/1402-4896/abfde1/meta
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Summary:In this study, Y3-xCdxFe5O12 (0.0 ≤ × ≤0.2) powders were synthesized via the co-precipitation method at calcination temperature 1100 °C. The phase formation of YIG was confirmed from X-ray powder diffraction (XRD) and Fourier Transform Infrared (FTIR) technique. The change of the band-gap energy, determined from the analysis of UV-visible spectroscopy, with the particle size was in agreement with the quantum confinement effect for x between 0.02 and 0.2. The magnetization study showed a non-monotonic change in the saturation magnetization and the coercivity with the increase of Cd2+ content. This behavior is an indication of both effect of particle size and the concentration of the doped Cadmium. The Mӧssbauer spectroscopy analysis confirmed the existence of Fe3+ in both octahedral and tetrahedral sites and the non-existence of Fe2+.