Nb-based MXenes for efficient electrochemical sensing of small biomolecules in the anodic potential

<p dir="ltr">In this work, we study the electrochemical performance of Nb<sub>2</sub>CT<sub>x</sub> and Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> MXenes in the aqueous media and their application as a sensing platform for sma...

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Main Author: P. Abdul Rasheed (4863283) (author)
Other Authors: Ravi P. Pandey (1449436) (author), Tricia Gomez (9624535) (author), Khadeeja A. Jabbar (16931796) (author), Kaitlyn Prenger (8587548) (author), Michael Naguib (1441495) (author), Brahim Aïssa (14157243) (author), Khaled A. Mahmoud (572646) (author)
Published: 2020
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Summary:<p dir="ltr">In this work, we study the electrochemical performance of Nb<sub>2</sub>CT<sub>x</sub> and Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> MXenes in the aqueous media and their application as a sensing platform for small biomolecules. Both Nb<sub>2</sub>CT<sub>x</sub> and Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> are electrochemically stable up to an anodic potential of 0.5 V. It was found that Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> is more electrochemically active than Nb<sub>2</sub>CT<sub>x</sub>. Based on this, Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> was evaluated for the electrochemical detection of aqueous media solutions containing ascorbic acid, uric acid and dopamine. This work opens the door for the wider application of Nb-based MXenes in aqueous electrochemical sensing applications.</p><h2>Other Information</h2><p dir="ltr">Published in: Electrochemistry Communications<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.elecom.2020.106811" target="_blank">https://dx.doi.org/10.1016/j.elecom.2020.106811</a></p>