Visible-Light-Driven Catalytic Dehalogenation of Trichloroacetic Acid and α‑Halocarbonyl Compounds: Multiple Roles of Copper

Visible-Light-Driven Catalytic Dehalogenation of Trichloroacetic Acid and α‑Halocarbonyl Compounds: Multiple Roles of Copper

Herein, we report the reaction development and mechanistic studies of visible-light-driven Cu-catalyzed dechlorination of trichloroacetic acid for the highly selective formation of monochloroacetic acid. Visible-light-driven transition metal catalysis via an inner-sphere pathway features the dual ro...

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Bibliographic Details
Main Author: Abigail J. Thillman (20752101) (author)
Other Authors: Erin C. Kill (20752104) (author), Alexander N. Erickson (16354533) (author), Dian Wang (228559) (author)
Published: 2025
Subjects:
Biophysics
Biochemistry
Ecology
Computational Biology
Environmental Sciences not elsewhere classified
Biological Sciences not elsewhere classified
Chemical Sciences not elsewhere classified
Information Systems not elsewhere classified
transition metal species
sphere pathway features
hydrogen atom source
highly selective formation
substrate activation steps
detailed mechanistic understanding
driven catalytic dehalogenation
mechanistic studies
detailed mechanism
catalytic method
thermal activation
state activation
driven cu
driven catalysis
trichloroacetic acid
ray crystallographic
monochloroacetic acid
kinetic studies
halocarboxylic acids
catalyzed dechlorination
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