Visible-Light-Driven Catalytic Dehalogenation of Trichloroacetic Acid and α‑Halocarbonyl Compounds: Multiple Roles of Copper

Herein, we report the reaction development and mechanistic studies of visible-light-driven Cu-catalyzed dechlorination of trichloroacetic acid for the highly selective formation of monochloroacetic acid. Visible-light-driven transition metal catalysis via an inner-sphere pathway features the dual ro...

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Bibliographic Details
Main Author:	Abigail J. Thillman (20752101) (author)
Other Authors:	Erin C. Kill (20752104) (author), Alexander N. Erickson (16354533) (author), Dian Wang (228559) (author)
Published:	2025
Subjects:	Biophysics Biochemistry Ecology Computational Biology Environmental Sciences not elsewhere classified Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified Information Systems not elsewhere classified transition metal species sphere pathway features hydrogen atom source highly selective formation substrate activation steps detailed mechanistic understanding driven catalytic dehalogenation mechanistic studies detailed mechanism catalytic method thermal activation state activation driven cu driven catalysis trichloroacetic acid ray crystallographic monochloroacetic acid kinetic studies halocarboxylic acids catalyzed dechlorination
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Visible-Light-Driven Catalytic Dehalogenation of Trichloroacetic Acid and α‑Halocarbonyl Compounds: Multiple Roles of Copper

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