Intramolecular Oxidative Addition Triggered by One-Electron Oxidation of Molybdenum(iii) Tris(anilide): Generation of Molybdenum(v) Imido Aryl Bis(anilide) by Autocatalysis

One-electron oxidation of molybdenum(iii) tris(anilide) Mo(N[tBu]Ar)3 (Ar: ArMe = 3,5-Me2C6H3 and ArPh = 3,5-Ph<sub&g...

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Bibliographic Details
Main Author:	Albert Paparo (6057257) (author)
Other Authors:	Tobias Schindler (716975) (author), Jan van Leusen (7818539) (author), Jessica Cook (11101554) (author), Thomas P. Spaniol (1588798) (author), Paul Kögerler (1483366) (author), Manuel Temprado (1446862) (author), Christopher C. Cummins (1460161) (author), Jun Okuda (1470157) (author)
Published:	2025
Subjects:	Biochemistry Medicine Cell Biology Genetics Molecular Biology Pharmacology Evolutionary Biology Ecology Immunology Marine Biology Cancer Inorganic Chemistry Infectious Diseases Computational Biology Chemical Sciences not elsewhere classified high activation barrier ipso </ sub 6 </ sub 2 </ sub far prevented mo </ sup >)]. </ sup >)] 1 </ sup n – c ar )< sub anilide ): generation 4 ′- bipyridine 3 </ sub bu )( ar ph </ sup imido aryl bis access stable mo </ sup aryl bis sup >< ></ sup neutral mo cationic mo theoretically shown reductive elimination oxidizing agent ligated anilide labile binding isomerizing spontaneously evans method epr spectroscopy electron oxidation electron configuration autocatalytic process
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