Harnessing Dynamic Heteroleptic Complexation for Self-Assembly of Robust Nested Metallo-Supramolecular Cages

Harnessing Dynamic Heteroleptic Complexation for Self-Assembly of Robust Nested Metallo-Supramolecular Cages

The exclusive formation of artificial multicomponent assemblies remains a significant challenge, in contrast to the well-established organization observed in natural systems, due to intrinsic entropic constraints. To overcome this limitation, recent efforts have been focused on developing precision...

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Main Author: Soumyakanta Prusty (4962682) (author)
Other Authors: Hung-Kai Hsu (3228069) (author), Mahesh Madasu (2623879) (author), Alisha Rani (22213450) (author), Jun-Hao Fu (2554720) (author), Lin-Ting Lin (8575338) (author), Ming-Hao Lee (6809288) (author), Ming-Wen Chu (1446301) (author), Chun-Hong Kuo (1448776) (author), Yi-Tsu Chan (2173042) (author)
Published: 2025
Subjects:
Biochemistry
Cell Biology
Molecular Biology
Developmental Biology
Space Science
Biological Sciences not elsewhere classified
Chemical Sciences not elsewhere classified
Physical Sciences not elsewhere classified
Information Systems not elsewhere classified
robust nested metallo
nested cage even
low concentrations allow
intrinsic entropic constraints
ideal complementary pair
established organization observed
robust nested cages
situ reductive formation
developing precision self
supramolecular cages
quantitative formation
exclusive formation
successful self
substituent bulkiness
structural characterization
stem ).
significant challenge
saxs ),
recent efforts
ray scattering
rational construction
natural systems
multivalent coordination
independently synthesized
improved solubility
gold nanoparticles
functional nanoreactor
exclusive manner
exceptional stability
based small
angle x
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