Examples of the four categories of stereochemical relationships of D- & L- hexitols after 180° rotation in plane: Altered absolute configurations of the chiral centers and their numbering from the parent aldohexose: Clockwise; Group I include galactitol (5a,b) and allitol (10a,b) both are <i>meso</i> compounds as D-and L-enantiomers are superimposable.

Examples of the four categories of stereochemical relationships of D- & L- hexitols after 180° rotation in plane: Altered absolute configurations of the chiral centers and their numbering from the parent aldohexose: Clockwise; Group I include galactitol (5a,b) and allitol (10a,b) both are <i>meso</i> compounds as D-and L-enantiomers are superimposable.

<p><b>Group II</b> includes iditol (<b>12a,b</b>) and mannitol (<b>11a,b</b>) (both D-and L- enantiomers); preserves respective enantiomeric identities(D-/L-). <b>Group III</b> includes altritol (<b>6a,b</b>) and talitol (<b>8a,...

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Bibliographic Details
Main Author:	Prithwiraj De (833532) (author)
Other Authors:	Jenna Salvat (21601648) (author), Eliza Walthers (21601651) (author), James Henriksen (21601654) (author), Michael Wells (381341) (author), Richard T. Conant (2902886) (author), Claudia M. Boot (2471227) (author)
Published:	2025
Subjects:	Biochemistry Microbiology Biotechnology Environmental Sciences not elsewhere classified Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified internal chiral carbons free expressed galactitol ten enantiopure hexitols enantiopure rare ketoses underlying stereochemical interplay g2dh oxidizes galactitol multiple enantiopure ketoses unconventional stereochemical investigation precludes kinetic analysis div >< p confirmed chemoenzymatic synthesis harnessing enzyme promiscuity harness enzyme promiscuity enzyme promiscuity due short chain dehydrogenase kinetic analysis chemoenzymatic investigation enantiopure ketohexoses enzyme promiscuity stereochemical foundation predictive synthesis g2dh ), chain conformation promiscuous enzyme enzyme stereospecificity multiple alditols vitro </ using cell systematic exploration structural basis s2dh ), right choice relative configurations product yields partial stereoselectivity nmr spectroscopy meso </ family catalyze evolutionary processes enzymatic operation dehydrogenase enzymes biotech industry also allows absolute configuration a5dh ), 2s 3s 2r 3s
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