Origin of a Kinetically Selective Route for Thermoreversible Valence Tautomerism-Based Photoswitching in O‑Heterocycles Containing Conjugated Dienes

The thermal electrocyclic ring opening of fused cis-cyclobutene to cis,cis-diene is prohibited according to the Woodward–Hoffmann (WH) rules; nonetheless, experiments provide firm evidence for their formation. However, the mechanism, electroni...

Full description

Saved in:

Bibliographic Details
Main Author:	Akanksha Ashok Sangolkar (19865681) (author)
Other Authors:	Anup Shahi (19865684) (author), Rama Krishna Kadiyam (18445612) (author), Ravinder Pawar (9629292) (author)
Published:	2024
Subjects:	Biophysics Biochemistry Genetics Biotechnology Cancer Infectious Diseases Plant Biology Computational Biology Chemical Sciences not elsewhere classified Physical Sciences not elsewhere classified woodward – hoffmann thermoreversible valence tautomerism thermal ring opening promotes c – outperform energy storage direct disrotatory pathway conrotatory ring opening kinetically selective route >- heterocycles containing kinetically refutes kinetically preferred >- dienes >- diene >- cyclobutene ultimately leads singlet biradicaloid results emphasize rational design prohibited according membered cyclic increased electrophilicity gain insights expected h electronic structure critical insight core skeleton conjugated diene bond rotation based photoswitching available h
Tags:	Add Tag No Tags, Be the first to tag this record!

Be the first to leave a comment!

Origin of a Kinetically Selective Route for Thermoreversible Valence Tautomerism-Based Photoswitching in <i>O</i>‑Heterocycles Containing Conjugated Dienes

Similar Items