Aluminum Complexes Bearing Aminoquinoline Ligands with Different Pendant Donors: Remarkable Impact of Hemilability on the Ring-Opening Polymerization of ε‑Caprolactone

Hemilabile ligands are highly promising components of advanced catalysts because their switchable coordination modes can trigger novel activation and stabilization mechanisms. Their increasing use has led to the successful development of stable, active, and selective catalysts. In this study, new al...

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Bibliographic Details
Main Author:	Sen Xiang (2898662) (author)
Other Authors:	Jinbo Zhang (3599318) (author), Shaofeng Liu (667160) (author), Pierre Braunstein (1415620) (author), Zhibo Li (1328010) (author)
Published:	2024
Subjects:	Biophysics Biochemistry Cell Biology Molecular Biology Immunology Chemical Sciences not elsewhere classified trigger novel activation switchable coordination modes pendant donor decreased large excess bnoh highly promising components hemilabile ligand coordination different pendant donors 2 × 10 phenoxyl (< b benzyl (< b g · mol al3 </ b al1 </ b n </ sub relative donor capacities 4 </ sup 31 </ sup >< sub 01 mol weight polycaprolactones successful development stabilization mechanisms selective catalysts remarkable impact opening polymerization increasing use immortal catalysis higher activity catalytic properties catalyst loading advanced catalysts 100 equiv
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Aluminum Complexes Bearing Aminoquinoline Ligands with Different Pendant Donors: Remarkable Impact of Hemilability on the Ring-Opening Polymerization of ε‑Caprolactone

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