Room-Temperature H2 Splitting and N2‑Hydrogenation Induced by a Neutral LuII Complex

The direct splitting of H2 and N2 molecules is a challenging reaction that is closely related to the Haber–Bosch ammonia synthesis process. Until now, such reactivity has never been observed in the case of molecular lanthanide species. Here, we show that...

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التفاصيل البيبلوغرافية
المؤلف الرئيسي:	Evangelos Papangelis (20831910) (author)
مؤلفون آخرون:	Luca Demonti (20831913) (author), Iker del Rosal (8556855) (author), Angus Shephard (20831916) (author), Laurent Maron (1346082) (author), Grégory Nocton (1478341) (author), Thomas Simler (1498453) (author)
منشور في:	2025
الموضوعات:	Biophysics Biochemistry Microbiology Genetics Molecular Biology Sociology Cancer Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified valent molecular rare ligand scaffold allows earth metal complexes molecular lanthanide species ii </ sup 2 –</ sup highly reactive lu 2 bar h 2 </ sub lanthanide chemistry unique lu temperature h smooth conditions neutral lu kinetically stable fully corroborated dft calculations coordinated diazenido closely related challenging reaction careful selection
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Room-Temperature H<sub>2</sub> Splitting and N<sub>2</sub>‑Hydrogenation Induced by a Neutral Lu<sup>II</sup> Complex

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