Rh(III)-Catalyzed Oxidant-Free Dehydrogenative Mizoroki–Heck-Type Reaction: Identification of Off-Cycle Processes Potentially Limiting Catalytic Turnover

Rh(III)-Catalyzed Oxidant-Free Dehydrogenative Mizoroki–Heck-Type Reaction: Identification of Off-Cycle Processes Potentially Limiting Catalytic Turnover

The Rh(III)-catalyzed dehydrogenative Mizoroki–Heck-type reaction (DMHR) has been extensively studied owing to its diverse synthetic applications. This transformation generally requires stoichiometric amounts of an external oxidant, H<sub>2</sub> acceptor, or internal oxidizing group for...

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Bibliographic Details
Main Author: Naohiro Hirako (21486062) (author)
Other Authors: Izumi Takayanagi (21486065) (author), Daisuke Hirayama (4396837) (author), Takeshi Yasui (387985) (author), Yoshihiko Yamamoto (1368621) (author)
Published: 2025
Subjects:
Biochemistry
Medicine
Environmental Sciences not elsewhere classified
Chemical Sciences not elsewhere classified
rhodium hydride species
extensively studied owing
diverse synthetic applications
cycle resting species
computational study revealed
pyrazoles underwent alkenylation
internal oxidizing group
highly efficient oxidant
efficient catalytic turnover
free dmhr involving
2 </ sub
catalytic turnover
oxidizing agent
alkenylation product
free dmhr
free conditions
type reaction
remains underdeveloped
reaction system
minimizing waste
migratory insertion
ideal method
formed via
external oxidant
directing groups
coupling product
combined experimental
carboxylic acids
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