Titanium Cluster Nuclearity Controls the Potential of Ti(IV/III) Reduction by Transfer Hydrogenation
Titanium-containing clusters can be photoreduced in the presence of a hydrogen donor to form catalytically active Ti(III) centers. The cluster nuclearity is hypothesized to impact the thermodynamics of this process. To probe this, we examine a series of titanium polyoxometalates ranging from 3 to 17...
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2025
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