Unveiling Phase Transition Dynamics Using Cryogenic Optical Microscopy in a Charge-Transfer Fe<sub>2</sub>Co<sub>2</sub> Switchable Molecular Material

Understanding the phase transition mechanism in switchable materials is crucial to optimizing their properties. In this study, we present the thermal electron transfer-coupled spin transition (ETCST) mechanism, revealed through the cryogenic optical microscopy (OM) measurements on a cyanide-bridged...

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Автор:	Buqin Xu (19639838) (author)
Інші автори:	Nour-El-Islam Belmouri (21762681) (author), Longhe Li (20938186) (author), Sadiya Sadiya (21762684) (author), Guillaume Bouchez (2319817) (author), Mouhamadou Sy (2388802) (author), Geoffrey Gontard (1813603) (author), Kamel Boukheddaden (1399912) (author), Yanling Li (269030) (author), Rodrigue Lescouëzec (1891204) (author)
Опубліковано:	2025
Предмети:	Biophysics Medicine Cell Biology Molecular Biology Computational Biology Chemical Sciences not elsewhere classified Physical Sciences not elsewhere classified cryogenic optical microscopy bridged square complex coupled spin transition bulk sample (< anisotropic propagation patterns 255 k ). three steps along thermal electron transfer strip domains form intermolecular interactions govern final step involves step thermal etcst slower etcst propagation >- axis covering vbik )< sub rapidly extend along 2 </ sub phase transition mechanism single crystal (< phase transition intermolecular interactions thermal etcst rapid propagation transfer fe >- axis etcst along single crystal crystal x 5 k 273 k (< b >< sub etcst progresses {[ fe vbik ligands unexpected complexity two types switchable materials structural analysis second type ray diffraction molecular switching mechanistic insight gradually widen first type first time direct visualization c </ ab </
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Unveiling Phase Transition Dynamics Using Cryogenic Optical Microscopy in a Charge-Transfer Fe<sub>2</sub>Co<sub>2</sub> Switchable Molecular Material

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