Enantioselective [2+2+2] Cycloaddition of Internal Alkynes to Access Axially Chiral Biaryl Hexasubstituted Benzene
Multisubstituted benzene is a fundamental building block commonly found in natural products, organic semiconductors, and chiral ligands. The asymmetric synthesis of multisubstituted benzene with sterically hindered axial surfaces remains a significant challenge in organic synthesis. Herein, we prese...
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2025
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