An Isolated Lithium <i>ortho</i>-Carboranyl Cuprate Complex for the Synthesis of Multiple-Carborane-Substituted Arenes from (Hetero)Aryl Bromides and Chlorides

Carborane-substituted arenes have emerged as versatile building blocks in medicinal chemistry, materials science, and coordination chemistry owing to the unique three-dimensional aromaticity, exceptional stability, and bioisosteric properties of carboranes. However, the existing synthetic routes to...

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Bibliographic Details
Main Author:	Yusei Hisata (22347524) (author)
Other Authors:	Daina Morishita (22347527) (author), Yoichi Hoshimoto (1457608) (author)
Published:	2025
Subjects:	Biophysics Biochemistry Genetics Molecular Biology Pharmacology Evolutionary Biology Environmental Sciences not elsewhere classified Chemical Sciences not elsewhere classified versatile building blocks thus severely limiting method provides access hitherto difficult transformation efficient “ dump lithium bis (< existing synthetic routes coordination chemistry owing stir ” synthesis cu center available synthetic chemistry isolated lithium medicinal chemistry unprecedented molecules unique three thereby converting scalable process paradigm shift oxidative addition materials science li center isophthalonitrile functions fused arenes exceptional stability diverse array dimensional aromaticity cu centers bioisosteric properties aryl halides aryl bromides >- carboran
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An Isolated Lithium <i>ortho</i>-Carboranyl Cuprate Complex for the Synthesis of Multiple-Carborane-Substituted Arenes from (Hetero)Aryl Bromides and Chlorides

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