CO Reduction to Ethylene and Cyclopropane via a Trappable Ruthenium Methylidene

CO Reduction to Ethylene and Cyclopropane via a Trappable Ruthenium Methylidene

Ruthenium complexes based on <i>cis</i>-[Ru(bpy)<sub>2</sub>(CO)<sub>2</sub>]<sup>2+</sup> (bpy is 2,2′-bipyridine) can reduce CO<sub>2</sub> and CO to C<sub>1</sub> products including methanol, but access to products containing...

Full description

Saved in:

Bibliographic Details
Main Author:	Allison M. Smith (18928748) (author)
Other Authors:	Stephen J. Tereniak (1535857) (author), Haley Cox (22387397) (author), Mehmed Z. Ertem (1293684) (author), Marsha D. Massey (6580061) (author), Cynthia K. Schauer (1894891) (author), Alexander J. M. Miller (7247360) (author)
Published:	2025
Subjects:	Biophysics Biochemistry Cell Biology Genetics Pharmacology Developmental Biology Cancer Infectious Diseases Chemical Sciences not elsewhere classified products including methanol mechanistic studies elucidating experimental evidence implicates 2 ′- bipyridine 2 +</ sup 3 </ sub 1 </ sub pyridine )]< sup warming generates ethylene multicarbon products ethylene unique reactivity profile 5 ′- dimethyl bpy ′)< sub bpy )< sub 2 </ sub ruthenium hydroxymethyl complex stable pyridine adduct cis </ ethylene complex bpy ′ ylide complexes undergoes protonolysis sufficiently nucleophilic successfully trapped room temperature reduction catalysts reaction pathway low temperature key intermediates key intermediate forming adducts appropriate nitrile
Tags:	Add Tag No Tags, Be the first to tag this record!

Cannot write session to /tmp/vufind_sessions/sess_sk0u3eppoeca73hdbkjbcc33j1