Magnetic and Phonon Excitations in Iron(III) Porphyrin Complexes Probed by Inelastic Neutron Scattering: Impact of the Perdeuteration of the Porphyrin Ligand

Magnetic and phonon excitations, among the fundamental properties of metal complexes, have been of intense interest. Phonons include both intramolecular and intermolecular (or lattice) vibrations. Few techniques effectively probe excitations below 400 cm<sup>–1</sup>, where many transiti...

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Номзүйн дэлгэрэнгүй
Үндсэн зохиолч:	Adiat A. Fakolujo (22070123) (author)
Бусад зохиолчид:	Alexandria N. Bone (13168780) (author), Brenda A. Smith (22070126) (author), Liguo Song (2331163) (author), Yongqiang Cheng (1428478) (author), Luke L. Daemen (1818202) (author), Andrey A. Podlesnyak (1507075) (author), Zi-Ling Xue (1414108) (author)
Хэвлэсэн:	2025
Нөхцлүүд:	Biophysics Biochemistry Physiology Biotechnology Chemical Sciences not elsewhere classified Physical Sciences not elsewhere classified inelastic neutron scattering incoherent neutron scattering density functional theory based selection rules porphyrin complexes probed giving phonon symmetries sup >–</ sup porphyrin ligand magnetic 2 –</ sup >< sub >< </ b >)] >< sub phonon excitations metal complexes vibrational spectrometer vibrational modes unlike ir thereby revealing reduced signal ray diffraction raman spectroscopies phonons include noise ratios magnetic transition latter leads larger background h atoms fundamental properties fe – experimental spectra crystal structure ></ sub 7 cm 5 k 400 cm 2 →
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Magnetic and Phonon Excitations in Iron(III) Porphyrin Complexes Probed by Inelastic Neutron Scattering: Impact of the Perdeuteration of the Porphyrin Ligand

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