Overcoming Conformational Complexity to Elucidate Selective Ethylene Tetramerization Behavior

The famous metallacycle mechanism for ethylene tetramerization has received serious attention in recent decades, as the possibility of further ring expansion may not ensure the specific formation of 1-octene. However, there are limited discussions available on a precise understanding of the ethylene...

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Bibliographic Details
Main Author:	Jiale Peng (20099928) (author)
Other Authors:	Long Chen (315739) (author), Mengyu Zhu (2848586) (author), Li Sun (4624) (author), Zuoxiang Zeng (2606638) (author), Zhen Liu (74646) (author)
Published:	2025
Subjects:	Biophysics Biochemistry Biotechnology Sociology Space Science Environmental Sciences not elsewhere classified Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified received serious attention limited discussions available highly flexible nine geometric constraint resulting famous metallacycle mechanism extended metallacycle pathway even high molecular computational results demonstrated next ethylene insertion weight polyethylene via ethylene tetramerization behavior overcoming conformational complexity ring expansion may ethylene tetramerization conformational complexity ring expansion membered ring unique boat specific formation selective formation recent decades rapidly eliminate precise understanding pnp complex octene via metallacycles plays mechanistic studies less likely key role higher oligomer elimination step defined cr chair form better understanding also highlights
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Overcoming Conformational Complexity to Elucidate Selective Ethylene Tetramerization Behavior

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