Oxidation of Alcohols to Carboxylates with N2O Catalyzed by Ruthenium(II)-CNC Complexes

Air-stable ruthenium(II) complexes based on a picoline-derived CNC pincer ligand, [RuH(CNC)(CO)L]X (L = PPh3, X = Br; L = CO, X = BF4), were...

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Opis bibliograficzny
1. autor:	José Bermejo (21575599) (author)
Kolejni autorzy:	Laura L. Santos (1999171) (author), Eleuterio Álvarez (1478242) (author), Joaquı́n López-Serrano (2090728) (author), Andrés Suárez (2084308) (author)
Wydane:	2025
Hasła przedmiotowe:	Biophysics Biochemistry Medicine Cell Biology Genetics Developmental Biology Computational Biology Environmental Sciences not elsewhere classified Chemical Sciences not elsewhere classified density functional theory complexes react readily strong bases (< hydroxy ruthenium species catalytically active ru 2 </ sub complexes based x </ stable ruthenium nucleophilic attack l </ involve ru intermediates based intermediate aldehyde formed alcoholate deprotonated cnc complex containing catalytic reaction catalytic cycle carboxylate product basic conditions aldehyde molecule
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Oxidation of Alcohols to Carboxylates with N<sub>2</sub>O Catalyzed by Ruthenium(II)-CNC Complexes