Importance of Ligand Fine-Tuning: Alkyne Metathesis with Molybdenum Alkylidyne Complexes Supported by Phenyl-<i>tert-</i>butoxysilanolate Ligands

Importance of Ligand Fine-Tuning: Alkyne Metathesis with Molybdenum Alkylidyne Complexes Supported by Phenyl-<i>tert-</i>butoxysilanolate Ligands

The phenyl-<i>tert</i>-butoxysilanols Ph­(<i>t</i>BuO)<sub>2</sub>SiOH and Ph<sub>2</sub>(<i>t</i>BuO)­SiOH were prepared and used for the synthesis of the molybdenum 2,4,6-trimethylbenzylidyne complexes [MesCMo­{OSi­(O<i>t</i>...

وصف كامل

محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Angelika Neitzel (20445819) (author)
مؤلفون آخرون: Tobias Ludwig (695886) (author), Dirk Bockfeld (4386772) (author), Thomas Bannenberg (1456060) (author), Matthias Tamm (1456063) (author)
منشور في: 2024
الموضوعات:
Biophysics
Biochemistry
Medicine
Cell Biology
Sociology
Cancer
Environmental Sciences not elsewhere classified
Chemical Sciences not elsewhere classified
Physical Sciences not elsewhere classified
ray diffraction analysis
pre -)­ catalysts
etc  mo
etc  cet
crystallographically characterized molybdenacyclobutadiene
>′ coordination mode
temperature nmr spectroscopy
buo )< sub
bu )< sub
bu )­ ph
labile metallacyclobutadiene complexes
buo )­ sioh
ph }< sub
2 </ sub
2 </ b
3 </ sub
1 </ b
available alkyne metathesis
sub ><
low temperature
alkyne metathesis
></ sub
tert </
n </
molybdenum 2
trimethylphenyl ).
trimethylbenzylidyne complexes
tert -</
terminal alkynes
single crystals
siloxide ligands
rare example
previous members
phenyl -<
molecular structures
mer -</
ligand fine
corresponding propylidyne
chelating κ
catalytic performance
butoxysilanolate ligands
alkylidyne complexes
[( et
3 –<
3 ).
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