Photochemistry and Thermal Chemistry in Polymeric Ceramic Precursors

While pyrolysis of polymeric precursors has gained attention for the additive manufacturing of ceramics, the high-temperature process is energy-inefficient and time-consuming. Recently, photochemistry has been suggested to reduce energy consumption and reaction time, but the microscopic mechanisms o...

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Bibliographic Details
Main Author:	Nabankur Dasgupta (6416735) (author)
Other Authors:	Kai Ito (10347974) (author), Thomas M. Linker (16807124) (author), Wataru Sugimoto (1826413) (author), Seyedmahmoud Mortazavi (22232929) (author), Rajiv K. Kalia (1781878) (author), Aiichiro Nakano (1403197) (author), Alexander T. Radosevich (1555162) (author), Kohei Shimamura (1656787) (author), Fuyuki Shimojo (1448527) (author), Adri van Duin (7125542) (author), Priya Vashishta (1781872) (author)
Published:	2025
Subjects:	Biophysics Biochemistry Medicine Genetics Molecular Biology Evolutionary Biology Inorganic Chemistry Computational Biology Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified photoexcitation causes scission multiscale simulation approach carbonyl carbon shifting precursor remains stable reveal distinct photochemical reduce energy consumption polymeric ceramic precursors longer time scales facile additive manufacturing ceramics toward achieving thermal reaction pathways polymeric precursors additive manufacturing thermal pathways reaction time acylsilane precursor thermal chemistry temperature process sustainable society sico clusters principles nonadiabatic photoexcited hole microscopic mechanisms many atoms mainly resulting initial stage gained attention design ultralow combines first
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Photochemistry and Thermal Chemistry in Polymeric Ceramic Precursors

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