Ligand-Controlled Chemo- and Enantiodivergent Rh(III)-Catalyzed Redox-Neutral Annulation of Aryl Hydroxamates with Cyclopropenes via C–H and C–C Activation

Asymmetric C–H bond functionalization employing rhodium catalysts has gained significant attention in the recent past, given the possibility of introducing chirality at the late stage in organic scaffolds. This strategy has been generally restricted to enantioselective approaches, but achieving enan...

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主要作者:	Marimuthu Bakkiyaraj (20716566) (author)
其他作者:	Poulomi Adak (22138544) (author), Pazhamalai Anbarasan (1555108) (author)
出版:	2025
主題:	Biophysics Biochemistry Microbiology Molecular Biology Biotechnology Immunology Developmental Biology Computational Biology require catalytic amounts iii )- catalyzed gained significant attention c – h c – c broad substrate scope offer high enantiodivergence binaphthyl alone contributes 3 ′- position 1 er ). high yields achieving enantiodivergence synthetic modification synthetic applicability substituents present substituents differentiates starting point stage functionalization recent past reaction involves organic scaffolds neutral annulation introducing chirality generally restricted enantioselective approaches enantiodivergent rh cyclopentadienyl moieties chiral cyclopentadienylrhodium c1 synthons aryl hydroxamates activated species 97 %)
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Ligand-Controlled Chemo- and Enantiodivergent Rh(III)-Catalyzed Redox-Neutral Annulation of Aryl Hydroxamates with Cyclopropenes via C–H and C–C Activation

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