SmI<sub>2</sub>-Mediated Radical Cyclizations Directed by a C−Si Bond
The use of a silicon stereocontrol element in cyclobutanol and cyclopentanol-forming cyclizations mediated by SmI<sub>2</sub> results in excellent diastereocontrol. The C−Si bond in the products of cyclization provides a versatile handle for further manipulation. An asymmetric route to c...
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2010
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