Operando Analysis of Nickel Catalyst Speciation in Reductive Biaryl Synthesis Using Thin Layer Electrochemistry and a Microelectrode

Operando Analysis of Nickel Catalyst Speciation in Reductive Biaryl Synthesis Using Thin Layer Electrochemistry and a Microelectrode

Operando insights into nickel speciation during nickel-catalyzed cross-electrophile coupling reactions could play a major role in advancing these reactions, but analytical methods capable of providing such insights have not yet been developed. In this study, we integrate a thin-layer electrode (TLE)...

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Bibliografiske detaljer
Hovedforfatter:	Buwanila T. Punchihewa (22688305) (author)
Andre forfattere:	Antonio Romero-Arenas (3110208) (author), Robert S. Paton (1281666) (author), Daniel J. Weix (1284837) (author), Shannon S. Stahl (1291731) (author), Mohammad Rafiee (1474582) (author)
Udgivet:	2025
Fag:	Biochemistry Medicine Ecology Infectious Diseases Environmental Sciences not elsewhere classified Biological Sciences not elsewhere classified analytical methods capable enable operando monitoring ii </ sup nickel catalyst speciation microelectrode operando insights catalyst speciation operando analysis nickel speciation yielding insight temporal evolution results establish reductive homocoupling major role layer electrode kinetic profiles including accumulation different quantities catalyzed cross bipyridyl ligand based intermediates aryl halides approach allows
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Operando Analysis of Nickel Catalyst Speciation in Reductive Biaryl Synthesis Using Thin Layer Electrochemistry and a Microelectrode
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