Vertically Expanded Crystalline Porous Covalent Organic Frameworks

Covalent organic frameworks (COFs) can be developed for molecular confinement and separation. However, their proximate π stacks limit the interlayer distance to be only 3–6 Å, which is too small for guests to enter. As a result, COFs block access to the <i>x</i>–<i>y</i> spac...

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التفاصيل البيبلوغرافية
المؤلف الرئيسي:	Shuailei Xie (19514217) (author)
مؤلفون آخرون:	Matthew A. Addicoat (1738672) (author), Donglin Jiang (1578616) (author)
منشور في:	2024
الموضوعات:	Biophysics Biochemistry Medicine Biotechnology Developmental Biology Computational Biology Space Science Environmental Sciences not elsewhere classified Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified vertically expanded frameworks polygonal π planes originally inaccessible interlayers create discrete apertures opening interlayer spaces limit guest entry resultant frameworks separate dimensional covalent cobalt cofs block access bidentate axial pillars guest access interlayer distance axial pillars guest molecules vapor sorption synthesizing two pot reaction porphyrin along pores along molecular length molecular confinement mixtures efficiently guided polymerization extended faces exit strictly discriminate benzene coordination bonds breakthrough experiments ambient conditions
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Vertically Expanded Crystalline Porous Covalent Organic Frameworks

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