Bicyclohexene-<i>peri</i>-naphthalenes: Scalable Synthesis, Diverse Functionalization, Efficient Polymerization, and Facile Mechanoactivation of Their Polymers

Pursuing polymers that can transform from a nonconjugated to a conjugated state under mechanical stress to significantly change their properties, we developed a new generation of ladder-type mechanophore monomers, bicyclo[2.2.0]hex-5-ene-<i>peri</i>-naphthalene (BCH-Naph), that can be...

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التفاصيل البيبلوغرافية
المؤلف الرئيسي:	Jinghui Yang (588241) (author)
مؤلفون آخرون:	Maggie Horst (20513968) (author), Sabrina H. Werby (9239839) (author), Lynette Cegelski (816292) (author), Noah Z. Burns (1266771) (author), Yan Xia (534241) (author)
منشور في:	2025
الموضوعات:	Biophysics Biochemistry Medicine Genetics Molecular Biology Biotechnology Space Science Chemical Sciences not elsewhere classified Physical Sciences not elsewhere classified polymers pursuing polymers even simple stirring 0 ] hex opening metathesis polymerization poly ( bch efficient polymerization wide range synthetic scalability solid states significantly change scalable synthesis romp ). poor substituents peri </ new generation naph ) naph ), multigram quantities mechanically activated mechanical stress low dispersity functional diversity facile mechanoactivation ene -< efficiently polymerized efficient romp diverse functionalization dilute solutions controlled mws conjugated state bicyclohexene -< allowing tuning >- naphthalenes >- naphthalene
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Bicyclohexene-<i>peri</i>-naphthalenes: Scalable Synthesis, Diverse Functionalization, Efficient Polymerization, and Facile Mechanoactivation of Their Polymers

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