Bioinspired Stereoselective Total Synthesis of the Caged Sesquiterpenoid Daphnepapytone A

Bioinspired Stereoselective Total Synthesis of the Caged Sesquiterpenoid Daphnepapytone A

The first total synthesis of the novel caged sesquiterpenoid daphnepapytone A is disclosed. Key reactions include a Pauson–Khand cycloaddition to provide oleodaphone, a bioinspired photoinduced [2 + 2] cycloaddition to forge the cyclobutane-containing caged skeleton, and a C–H oxidation and reductio...

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Bibliographic Details
Main Author: Yan Zhang (8098) (author)
Other Authors: Pengfei Yu (680800) (author), Wei Chen (23863) (author), Jia Li (160557) (author), Kai Liu (159026) (author), Xingang Xie (1332975) (author), Huilin Li (795365) (author), Xuegong She (1332972) (author)
Published: 2025
Subjects:
Microbiology
Molecular Biology
Physiology
Inorganic Chemistry
Infectious Diseases
Chemical Sciences not elsewhere classified
step synthetic sequence
key reactions include
first total synthesis
exclusively stereoselective fashion
containing caged skeleton
caged sesquiterpenoid daphnepapytone
generate daphnepapytone
reduction protocol
provide oleodaphone
protecting group
bioinspired photoinduced
4 steps
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