Polymorphic Lattice and Conformational Effects on the Spin Crossover of [(TpMe,Me)2Fe]

The scorpionate sandwich complex [(TpMe,Me)2Fe], where TpMe,Me is hydrotris(3,5-dimethyl-1-pyrazolyl)borate, has long been of interest because it exhibits spin crossover in the solid state. Previous X-ray crystallographic studies r...

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Detalhes bibliográficos
Autor principal:	Javad Shokraiyan (21807711) (author)
Outros Autores:	Vahdat Jahed (21807714) (author), Gordon T. Yee (1847068) (author), Salah Eddin El Jamal (16445792) (author), Curtis E. Moore (1338609) (author), Michael P. Jensen (1405516) (author)
Publicado em:	2025
Assuntos:	Biophysics Biochemistry Physiology Pharmacology Biotechnology Cancer Chemical Sciences not elsewhere classified Physical Sciences not elsewhere classified – n bonds every example crystallized different intermolecular contacts central metal ion alternative trigonal polymorph 298 k confirms 6 </ sub exhibits spin crossover isomorphous trigonal lattice known [( tp 2 </ sub 298 k spin crossover [( tp ></ sub >< sub 100 k polymorphic lattice lattice packing spin state spin (< undistorted conformation solid state nearly ideal low temperature ligand conformation including low falls exactly dividing line distorted conformation conformational effects complexes indicates complex crystallizes complex adopts becomes low
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Polymorphic Lattice and Conformational Effects on the Spin Crossover of [(Tp<sup>Me,Me</sup>)<sub>2</sub>Fe]

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