Cross-Electrophile Coupling to Form Sterically Hindered C(sp2)–C(sp3) Bonds: Ni and Co Afford Complementary Reactivity

The formation of sterically hindered C(sp2)–C(sp3) bonds could be a useful synthetic tool but has been understudied in cross-electrophile coupling. Here, we report two methods that couple secondary alkyl bromides with aryl halides that contain sterically...

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التفاصيل البيبلوغرافية
المؤلف الرئيسي:	Tianrui Wu (20845223) (author)
مؤلفون آخرون:	Anthony J. Castro (8128224) (author), Kasturi Ganguli (13876916) (author), Madeline E. Rotella (7315112) (author), Ning Ye (396809) (author), Fabrice Gallou (1520266) (author), Bin Wu (138543) (author), Daniel J. Weix (1284837) (author)
منشور في:	2025
الموضوعات:	Biophysics Biochemistry Cell Biology Molecular Biology Physiology Evolutionary Biology Sociology Cancer Environmental Sciences not elsewhere classified Chemical Sciences not elsewhere classified useful synthetic tool sterically hindered c report two methods reductive elimination steps previously unknown complementarity >- substituted arenes yielding di -< ar • formation di -< yet understood studies demonstrate stoichiometric experiments radical capture oxidative addition ortho </ electrophile coupling atom transfer aryl halides
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Cross-Electrophile Coupling to Form Sterically Hindered C(sp<sup>2</sup>)–C(sp<sup>3</sup>) Bonds: Ni and Co Afford Complementary Reactivity

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