Large Hyperfine Coupling Arising from Pseudo‑<sup>2</sup>S Ground States in a Series of Lutetium(II) Metallocene Complexes

The synthesis of molecules with strong coupling between electronic and nuclear spins represents an important challenge in molecular quantum information science. Here, we report the synthesis and characterization of the divalent lutetium metallocene complexes Lu(Cp<sup>Me<sub>5</sub&g...

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المؤلف الرئيسي:	Danh X. Ngo (6110606) (author)
مؤلفون آخرون:	K. Randall McClain (1453753) (author), Jakub Hrubý (18011418) (author), Yannick J. Franzke (6269168) (author), Krishnendu Kundu (1627648) (author), Hyunchul Kwon (8550282) (author), Colin A. Gould (11718795) (author), Benjamin G. Harvey (1265289) (author), Stephen Hill (1262349) (author), Jeffrey R. Long (1341528) (author)
منشور في:	2025
الموضوعات:	Biophysics Biochemistry Cell Biology Neuroscience Physiology Evolutionary Biology Space Science Environmental Sciences not elsewhere classified Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified Physical Sciences not elsewhere classified nuclear spins represents largest yet reported largest yet observed general strategy toward 17 ghz across shell isolable complex pseudo ‑< sup strong hyperfine coupling lu ( cp line spectra indicates extremely large splitting computational analysis show et </ sup iso </ sub 2 </ sup orbital character  2 </ sub strong coupling 2 % molecular orbital lanthanide complex g </ sup >< >< sub tetraisopropylcyclopentadienyl ). slight deviation results outline ray diffraction molecular structures important challenge ground states free electron ethyltetraisopropylcyclopentadienyl ), crystal x 9 ° 6 °.
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Large Hyperfine Coupling Arising from Pseudo‑<sup>2</sup>S Ground States in a Series of Lutetium(II) Metallocene Complexes

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