Shapeshifting Ligands Mask Lewis Acidity of Dicationic Palladium(II)

Supporting ligands limit the degree of electrophilic activation for any substrate because they also reduce the Lewis acidity of the transition metal ion. Here, we temporarily mask the Lewis acidity of dicationic Pd(II) by using “shapeshifting” bidentate pyrimidine/olefin ligands <b>L1</b>...

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التفاصيل البيبلوغرافية
المؤلف الرئيسي:	Karli D. Sipps (20313315) (author)
مؤلفون آخرون:	Wyatt A. Gibbs (20313318) (author), Elvira R. Sayfutyarova (6372743) (author), Jonathan L. Kuo (1997809) (author)
منشور في:	2024
الموضوعات:	Biophysics Biochemistry Space Science Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified transition metal ion structurally static counterparts polar functional groups case study suggests 2 +</ sup supporting ligands limit distributed across pd l1 </ b appear charge separated charge separated solvated pd olefin ligands ligands delocalize dicationic pd temporarily mask react comparably property originates ligand ), lewis bases lewis acidity electrophilic activation dicationic palladium also reduce advantageous relative [< b
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Shapeshifting Ligands Mask Lewis Acidity of Dicationic Palladium(II)

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